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Hauptverfasser: Xiong, Zixiang, Zhu, Jian, Geng, Xueqian, Wen, Zheng, Zhang, Yongcheng, Liu, Jianyi
Format: Preprint
Veröffentlicht: 2025
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Online-Zugang:https://arxiv.org/abs/2504.21588
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author Xiong, Zixiang
Zhu, Jian
Geng, Xueqian
Wen, Zheng
Zhang, Yongcheng
Liu, Jianyi
author_facet Xiong, Zixiang
Zhu, Jian
Geng, Xueqian
Wen, Zheng
Zhang, Yongcheng
Liu, Jianyi
contents Transparent piezoelectric ceramics (TPCs) have great application potential in electro-optical-mechanical multi-functional devices. Preparing high-performance TPCs, especially improving the transparency through microstructure regulation, has recently caused extensive discussion. However, there is still controversy about the influence of grains and pores on the transmittance of ceramics, and there is arbitrariness in the estimation of the theoretical transmittance limit. In this paper, taking PMN-PT-based ceramics as an example, theoretical mechanisms for the transmittance are discussed. An inhomogeneous reflection model is derived to improve the theoretical limit of transmittance. The effects of pores and grains scattering on transmittance are investigated. Rayleigh and RGD approximation are discussed to reveal the underlying scattering mechanisms. It is found that Rayleigh approximation is suitable for describing pore scattering, while RGD approximation is suitable for grain scattering. Thus, a Rayleigh-RGD combined model is proposed to describe light scattering in TPCs and successfully employed to fit experimentally measured transmittance curves.
format Preprint
id arxiv_https___arxiv_org_abs_2504_21588
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Theoretical modeling of synergistic effect of pores and grains on transmittance in transparent piezoelectric ceramics
Xiong, Zixiang
Zhu, Jian
Geng, Xueqian
Wen, Zheng
Zhang, Yongcheng
Liu, Jianyi
Materials Science
Transparent piezoelectric ceramics (TPCs) have great application potential in electro-optical-mechanical multi-functional devices. Preparing high-performance TPCs, especially improving the transparency through microstructure regulation, has recently caused extensive discussion. However, there is still controversy about the influence of grains and pores on the transmittance of ceramics, and there is arbitrariness in the estimation of the theoretical transmittance limit. In this paper, taking PMN-PT-based ceramics as an example, theoretical mechanisms for the transmittance are discussed. An inhomogeneous reflection model is derived to improve the theoretical limit of transmittance. The effects of pores and grains scattering on transmittance are investigated. Rayleigh and RGD approximation are discussed to reveal the underlying scattering mechanisms. It is found that Rayleigh approximation is suitable for describing pore scattering, while RGD approximation is suitable for grain scattering. Thus, a Rayleigh-RGD combined model is proposed to describe light scattering in TPCs and successfully employed to fit experimentally measured transmittance curves.
title Theoretical modeling of synergistic effect of pores and grains on transmittance in transparent piezoelectric ceramics
topic Materials Science
url https://arxiv.org/abs/2504.21588