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Hauptverfasser: Kato, Ryoma, Yoshida, Ten-ichiro, Iimori, Riku, Zizhou, Tai, Shiga, Masanobu, Inagaki, Yuji, Kimura, Takashi, Ienaga, Koichiro, Kawae, Tatsuya
Format: Preprint
Veröffentlicht: 2025
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Online-Zugang:https://arxiv.org/abs/2505.01960
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author Kato, Ryoma
Yoshida, Ten-ichiro
Iimori, Riku
Zizhou, Tai
Shiga, Masanobu
Inagaki, Yuji
Kimura, Takashi
Ienaga, Koichiro
Kawae, Tatsuya
author_facet Kato, Ryoma
Yoshida, Ten-ichiro
Iimori, Riku
Zizhou, Tai
Shiga, Masanobu
Inagaki, Yuji
Kimura, Takashi
Ienaga, Koichiro
Kawae, Tatsuya
contents Hydrogen exhibits quantum phenomena, such as tunneling in materials. According to theory, the quantum properties of hydrogen change significantly in superconductors due to the emergence of an energy gap on the Fermi surface, which reduces the interaction between hydrogen nucleus (i.e., proton) and conduction electrons. This reduction is predicted to enhance the tunneling probability of protons. Here, we report the double transitions of the electrical resistivity in high-quality palladium hydride (PdHx) and deuteride (PdDx) prepared by low-temperature absorption below T = 180 K. After a sharp drop in the resistivity at T ~ 2 K owing to the superconducting transition of PdH(D)x, a large residual resistivity remained. Additionally, the resistivity dropped to zero below T = 1 K. The experimental results suggest that the quantum tunneling of highly concentrated protons (deuterons) in the superconducting state is responsible for the observed features: the residual resistivity arises from the weakening of the global coherence of superconductivity owing to the tunneling motion of protons (deuterons), while the zero resistivity is caused by long-range ordering of the protons (deuterons). This system offers a new platform for investigating the quantum many-body properties of tunneling particles.
format Preprint
id arxiv_https___arxiv_org_abs_2505_01960
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle New quantum state formed by highly concentrated protons in superconducting palladium hydride
Kato, Ryoma
Yoshida, Ten-ichiro
Iimori, Riku
Zizhou, Tai
Shiga, Masanobu
Inagaki, Yuji
Kimura, Takashi
Ienaga, Koichiro
Kawae, Tatsuya
Superconductivity
Hydrogen exhibits quantum phenomena, such as tunneling in materials. According to theory, the quantum properties of hydrogen change significantly in superconductors due to the emergence of an energy gap on the Fermi surface, which reduces the interaction between hydrogen nucleus (i.e., proton) and conduction electrons. This reduction is predicted to enhance the tunneling probability of protons. Here, we report the double transitions of the electrical resistivity in high-quality palladium hydride (PdHx) and deuteride (PdDx) prepared by low-temperature absorption below T = 180 K. After a sharp drop in the resistivity at T ~ 2 K owing to the superconducting transition of PdH(D)x, a large residual resistivity remained. Additionally, the resistivity dropped to zero below T = 1 K. The experimental results suggest that the quantum tunneling of highly concentrated protons (deuterons) in the superconducting state is responsible for the observed features: the residual resistivity arises from the weakening of the global coherence of superconductivity owing to the tunneling motion of protons (deuterons), while the zero resistivity is caused by long-range ordering of the protons (deuterons). This system offers a new platform for investigating the quantum many-body properties of tunneling particles.
title New quantum state formed by highly concentrated protons in superconducting palladium hydride
topic Superconductivity
url https://arxiv.org/abs/2505.01960