Intrinsic Attractive and Repulsive Interactions: From Classical to Quantum Gases in the Generalized Maxwell-Boltzmann Distribution

Fuente: arXiv
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Autori principali: Seifi, Maryam, Ebadi, Zahra, Agahi, Hamzeh, Mehri-Dehnavi, Hossein, Mohammadzadeh, Hosein
Natura: Preprint
Pubblicazione: 2025
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author Seifi, Maryam
Ebadi, Zahra
Agahi, Hamzeh
Mehri-Dehnavi, Hossein
Mohammadzadeh, Hosein
author_facet Seifi, Maryam
Ebadi, Zahra
Agahi, Hamzeh
Mehri-Dehnavi, Hossein
Mohammadzadeh, Hosein
contents The thermodynamic parameter space is flat for an ideal classical gas with non-interacting particles. In contrast, for an ideal quantum Bose (Fermi) gas, the thermodynamic curvature is positive (negative), indicating intrinsic attractive (repulsive) interactions. We generalize the classical Maxwell-Boltzmann distribution by employing a generalized form of the exponential function, proposing the Mittag-Leffler Maxwell-Boltzmann distribution within the framework of superstatistics. We demonstrate that the generalization parameter, $α$, quantifies the statistical interaction. When $α= 1$, the distribution coincides with the standard classical Maxwell-Boltzmann distribution, where no statistical interaction is present. For $0 < α< 1$ ($α> 1$), the statistical interaction is repulsive (attractive), corresponding to a negative (positive) thermodynamic curvature of the system.
format Preprint
id arxiv_https___arxiv_org_abs_2505_03486
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Intrinsic Attractive and Repulsive Interactions: From Classical to Quantum Gases in the Generalized Maxwell-Boltzmann Distribution
Seifi, Maryam
Ebadi, Zahra
Agahi, Hamzeh
Mehri-Dehnavi, Hossein
Mohammadzadeh, Hosein
Statistical Mechanics
The thermodynamic parameter space is flat for an ideal classical gas with non-interacting particles. In contrast, for an ideal quantum Bose (Fermi) gas, the thermodynamic curvature is positive (negative), indicating intrinsic attractive (repulsive) interactions. We generalize the classical Maxwell-Boltzmann distribution by employing a generalized form of the exponential function, proposing the Mittag-Leffler Maxwell-Boltzmann distribution within the framework of superstatistics. We demonstrate that the generalization parameter, $α$, quantifies the statistical interaction. When $α= 1$, the distribution coincides with the standard classical Maxwell-Boltzmann distribution, where no statistical interaction is present. For $0 < α< 1$ ($α> 1$), the statistical interaction is repulsive (attractive), corresponding to a negative (positive) thermodynamic curvature of the system.
title Intrinsic Attractive and Repulsive Interactions: From Classical to Quantum Gases in the Generalized Maxwell-Boltzmann Distribution
topic Statistical Mechanics
url https://arxiv.org/abs/2505.03486