Second roton feature in the strongly coupled electron liquid

Fuente: arXiv
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Main Authors: Chuna, Thomas M., Vorberger, Jan, Tolias, Panagiotis, Robles, Alexander Benedix, Hecht, Michael, Hofmann, Phil-Alexander, Moldabekov, Zhandos A., Dornheim, Tobias
Format: Preprint
Published: 2025
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author Chuna, Thomas M.
Vorberger, Jan
Tolias, Panagiotis
Robles, Alexander Benedix
Hecht, Michael
Hofmann, Phil-Alexander
Moldabekov, Zhandos A.
Dornheim, Tobias
author_facet Chuna, Thomas M.
Vorberger, Jan
Tolias, Panagiotis
Robles, Alexander Benedix
Hecht, Michael
Hofmann, Phil-Alexander
Moldabekov, Zhandos A.
Dornheim, Tobias
contents We present extensive \emph{ab initio} path integral Monte Carlo (PIMC) results for the dynamic properties of the finite temperature uniform electron gas (UEG) over a broad range of densities, $2\leq r_s\leq300$. We demonstrate that the direct analysis of the imaginary-time density--density correlation function (ITCF) allows for a rigorous assessment of the density and temperature dependence of the previously reported roton-type feature [T.~Dornheim, \emph{Phys.~Rev.~Lett.}~\textbf{121}, 255001 (2018)] at intermediate wavenumbers. We clearly resolve the emergence of a second roton at the second harmonic of the original feature for $r_s\gtrsim100$, which we identify as an incipient phonon dispersion. Finally, we use our highly accurate PIMC results for the ITCF as the basis for an analytic continuation to compute the dynamic structure factor, which additionally substantiates the existence of the second roton in the strongly coupled electron liquid. Our investigation further elucidates the complex interplay between quantum delocalization and Coulomb coupling in the UEG. All PIMC results are freely available online and provide valuable benchmarks for other theoretical methodologies and approximations.
format Preprint
id arxiv_https___arxiv_org_abs_2505_11150
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Second roton feature in the strongly coupled electron liquid
Chuna, Thomas M.
Vorberger, Jan
Tolias, Panagiotis
Robles, Alexander Benedix
Hecht, Michael
Hofmann, Phil-Alexander
Moldabekov, Zhandos A.
Dornheim, Tobias
Chemical Physics
Quantum Gases
Strongly Correlated Electrons
We present extensive \emph{ab initio} path integral Monte Carlo (PIMC) results for the dynamic properties of the finite temperature uniform electron gas (UEG) over a broad range of densities, $2\leq r_s\leq300$. We demonstrate that the direct analysis of the imaginary-time density--density correlation function (ITCF) allows for a rigorous assessment of the density and temperature dependence of the previously reported roton-type feature [T.~Dornheim, \emph{Phys.~Rev.~Lett.}~\textbf{121}, 255001 (2018)] at intermediate wavenumbers. We clearly resolve the emergence of a second roton at the second harmonic of the original feature for $r_s\gtrsim100$, which we identify as an incipient phonon dispersion. Finally, we use our highly accurate PIMC results for the ITCF as the basis for an analytic continuation to compute the dynamic structure factor, which additionally substantiates the existence of the second roton in the strongly coupled electron liquid. Our investigation further elucidates the complex interplay between quantum delocalization and Coulomb coupling in the UEG. All PIMC results are freely available online and provide valuable benchmarks for other theoretical methodologies and approximations.
title Second roton feature in the strongly coupled electron liquid
topic Chemical Physics
Quantum Gases
Strongly Correlated Electrons
url https://arxiv.org/abs/2505.11150