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Autores principales: Bittner, Eric R, Silva-Acuna, Carlos
Formato: Preprint
Publicado: 2025
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Acceso en línea:https://arxiv.org/abs/2505.11450
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author Bittner, Eric R
Silva-Acuna, Carlos
author_facet Bittner, Eric R
Silva-Acuna, Carlos
contents We present a velocity-gauge formalism for computing nonlinear current response functions in periodic systems and apply it to the Su-Schrieffer-Heeger (SSH) model as a minimal topological testbed. By retaining the full minimal coupling Hamiltonian and avoiding the rotating wave approximation, we construct gauge-consistent expressions for the linear and third-order current susceptibilities using retarded Green's functions. Our results reveal how nonlinear optical spectra encode not only energy-level transitions but also interband phase coherence and topological winding. In the topological phase, the third-order response exhibits characteristic phase inversions and spectral asymmetries that are absent in the trivial phase. These features reflect geometric changes in the Bloch eigenstates and highlight the role of virtual pathways in shaping the nonlinear signal. Our framework offers a robust and extensible platform for modeling nonlinear light-matter interactions in topological materials beyond the dipole approximation and the standard Coulomb-gauge formulation in molecular spectroscopy.
format Preprint
id arxiv_https___arxiv_org_abs_2505_11450
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Coherent Spectroscopic Probes of Topology: A Velocity-Gauge Perspective
Bittner, Eric R
Silva-Acuna, Carlos
Chemical Physics
Mesoscale and Nanoscale Physics
Materials Science
We present a velocity-gauge formalism for computing nonlinear current response functions in periodic systems and apply it to the Su-Schrieffer-Heeger (SSH) model as a minimal topological testbed. By retaining the full minimal coupling Hamiltonian and avoiding the rotating wave approximation, we construct gauge-consistent expressions for the linear and third-order current susceptibilities using retarded Green's functions. Our results reveal how nonlinear optical spectra encode not only energy-level transitions but also interband phase coherence and topological winding. In the topological phase, the third-order response exhibits characteristic phase inversions and spectral asymmetries that are absent in the trivial phase. These features reflect geometric changes in the Bloch eigenstates and highlight the role of virtual pathways in shaping the nonlinear signal. Our framework offers a robust and extensible platform for modeling nonlinear light-matter interactions in topological materials beyond the dipole approximation and the standard Coulomb-gauge formulation in molecular spectroscopy.
title Coherent Spectroscopic Probes of Topology: A Velocity-Gauge Perspective
topic Chemical Physics
Mesoscale and Nanoscale Physics
Materials Science
url https://arxiv.org/abs/2505.11450