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| Main Authors: | , , , , , , |
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| Format: | Preprint |
| Published: |
2025
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| Subjects: | |
| Online Access: | https://arxiv.org/abs/2505.13956 |
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Table of Contents:
- Expanding the operational range of luminescent thermometers that utilize thermally induced structural phase transitions in lanthanide-doped materials necessitates the exploration of novel host matrices with diverse thermal behaviors. In line with this objective, the present study offers a comprehensive analysis of the temperature-dependent spectroscopic properties of Li3Sc2(PO4)3:Eu3+. The findings reveal that the studied material undergoes two reversible phase transitions: γLT - α/\b{eta} phase transition at approximately 160 K, followed by an \b{eta} HT transition around 550 K. These transitions are evidenced by notable alterations in the emission spectra and luminescence decay kinetics of Eu3+ ions. By employing an appropriate luminescence intensity ratio, the sensitivity was determined to be 7.8 % K-1 at 160 K for 0.1%Eu3+ and 0.65 % K-1 at 550 K for 0.5%Eu3+. Furthermore, the study demonstrates that the phase transition temperature in Li3Sc2(PO4)3:Eu3+ can be modulated through variations in dopant ion concentration and annealing conditions, which in turn influence the material's morphology. These strategies enable the fine-tuning of thermometric performance in phase transition-based luminescent thermometers. To the best of our knowledge, this represents the first report in the literature of a luminescent thermometer exhibiting dual thermal operating ranges.