Tailoring the Electronic Configurations of YPc$_2$ on Cu(111): Decoupling Strategies for Molecular Spin Qubits Platforms
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| Main Authors: | , , , , , , , , , , , |
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| Format: | Preprint |
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2025
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| author | Oh, Soyoung Cho, Franklin. H. Soe, We-hyo Yu, Jisoo Bui, Hong Spree, Lukas Hommel, Caroline Jang, Wonjun Phark, Soo-hyon Colazzo, Luciano Wolf, Christoph Donati, Fabio |
| author_facet | Oh, Soyoung Cho, Franklin. H. Soe, We-hyo Yu, Jisoo Bui, Hong Spree, Lukas Hommel, Caroline Jang, Wonjun Phark, Soo-hyon Colazzo, Luciano Wolf, Christoph Donati, Fabio |
| contents | Among the potential spin qubit candidates, yttrium phthalocyanine double-decker (YPc$_2$) features a diamagnetic metal ion core that stabilizes the molecular structure, while its magnetic properties arise primarily from an unpaired electron (S=1/2) delocalized over the two phthalocyanine (Pc) ligands. Understanding its properties in the proximity of metal electrodes is crucial to assess its potential use in molecular spin qubits architectures. Here, we investigated the morphology and electronic structure of this molecule adsorbed on Cu(111) surface using scanning tunneling microscopy (STM). On Cu(111), YPc$_2$ adsorbs flat, with isolated molecules showing a preferred orientation along the <111> crystal axes. Moreover, we observed two different types of self-assembly molecular packing when growing molecular patches. For YPc$_2$ in direct contact with Cu(111), STM revealed a widely separated highest occupied and lowest unoccupied molecular orbitals (HOMO/LUMO), suggesting the quenching of the unpaired spin. Conversely, when YPc$_2$ is separated from the metal substrate by a few-layer thick diamagnetic zinc phthalocyanine (ZnPc) layer, we found the HOMO to split into singly occupied and singly unoccupied molecular orbitals (SOMO/SUMO). We observed that more than 2 layers of ZnPc are needed to avoid intermixing between the two molecules and spin quenching in YPc2. Density functional theory (DFT) reveals the spin quenching is due to the hybridization between YPc$_2$ and Cu(111) states, confirming the importance of using suitable decoupling layers to preserve the unpaired molecular spin. Our results suggest the potential of YPc$_2$/ZnPc heterostructures as a stable and effective molecular spin qubit platform and validate the possibility of integrating this molecular spin qubit candidate in future quantum logic devices. |
| format | Preprint |
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arxiv_https___arxiv_org_abs_2505_15539 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Tailoring the Electronic Configurations of YPc$_2$ on Cu(111): Decoupling Strategies for Molecular Spin Qubits Platforms Oh, Soyoung Cho, Franklin. H. Soe, We-hyo Yu, Jisoo Bui, Hong Spree, Lukas Hommel, Caroline Jang, Wonjun Phark, Soo-hyon Colazzo, Luciano Wolf, Christoph Donati, Fabio Mesoscale and Nanoscale Physics Chemical Physics Among the potential spin qubit candidates, yttrium phthalocyanine double-decker (YPc$_2$) features a diamagnetic metal ion core that stabilizes the molecular structure, while its magnetic properties arise primarily from an unpaired electron (S=1/2) delocalized over the two phthalocyanine (Pc) ligands. Understanding its properties in the proximity of metal electrodes is crucial to assess its potential use in molecular spin qubits architectures. Here, we investigated the morphology and electronic structure of this molecule adsorbed on Cu(111) surface using scanning tunneling microscopy (STM). On Cu(111), YPc$_2$ adsorbs flat, with isolated molecules showing a preferred orientation along the <111> crystal axes. Moreover, we observed two different types of self-assembly molecular packing when growing molecular patches. For YPc$_2$ in direct contact with Cu(111), STM revealed a widely separated highest occupied and lowest unoccupied molecular orbitals (HOMO/LUMO), suggesting the quenching of the unpaired spin. Conversely, when YPc$_2$ is separated from the metal substrate by a few-layer thick diamagnetic zinc phthalocyanine (ZnPc) layer, we found the HOMO to split into singly occupied and singly unoccupied molecular orbitals (SOMO/SUMO). We observed that more than 2 layers of ZnPc are needed to avoid intermixing between the two molecules and spin quenching in YPc2. Density functional theory (DFT) reveals the spin quenching is due to the hybridization between YPc$_2$ and Cu(111) states, confirming the importance of using suitable decoupling layers to preserve the unpaired molecular spin. Our results suggest the potential of YPc$_2$/ZnPc heterostructures as a stable and effective molecular spin qubit platform and validate the possibility of integrating this molecular spin qubit candidate in future quantum logic devices. |
| title | Tailoring the Electronic Configurations of YPc$_2$ on Cu(111): Decoupling Strategies for Molecular Spin Qubits Platforms |
| topic | Mesoscale and Nanoscale Physics Chemical Physics |
| url | https://arxiv.org/abs/2505.15539 |