Sensing single molecule magnets with nitrogen vacancy centers

Fuente: arXiv
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Main Authors: Smooha, Ariel, Kumar, Jitender, Yudilevich, Dan, Rosenberg, John W., Bayer, Valentin, Stöhr, Rainer, Denisenko, Andrej, Bendikov, Tatyana, Kossoy, Anna, Pinkas, Iddo, Tan, Hengxin, Yan, Binghai, Sarjar, Biprajit, van Slageren, Joris, Finkler, Amit
Format: Preprint
Published: 2025
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author Smooha, Ariel
Kumar, Jitender
Yudilevich, Dan
Rosenberg, John W.
Bayer, Valentin
Stöhr, Rainer
Denisenko, Andrej
Bendikov, Tatyana
Kossoy, Anna
Pinkas, Iddo
Tan, Hengxin
Yan, Binghai
Sarjar, Biprajit
van Slageren, Joris
Finkler, Amit
author_facet Smooha, Ariel
Kumar, Jitender
Yudilevich, Dan
Rosenberg, John W.
Bayer, Valentin
Stöhr, Rainer
Denisenko, Andrej
Bendikov, Tatyana
Kossoy, Anna
Pinkas, Iddo
Tan, Hengxin
Yan, Binghai
Sarjar, Biprajit
van Slageren, Joris
Finkler, Amit
contents Single-molecule magnets (SMMs) are molecules that can function as nanoscale magnets with potential use as magnetic memory bits. While SMMs can retain magnetization at low temperatures, characterizing them on surface and at room temperature remains challenging and requires specialized nanoscale techniques. Here, we use single nitrogen-vacancy (NV) centers in diamond as highly sensitive, broadband magnetic field sensors to detect the magnetic noise of cobalt-based SMMs deposited on a diamond surface. We measure the NV relaxation and decoherence times at 296 K and at 5-8 K, observing a significant influence of the SMMs on them. From this, we can infer the SMMs' magnetic noise spectral density (NSD) and underlying magnetic properties. Moreover, we observe the effect of an applied magnetic field on the SMMs' NSD at low temperatures. The method provides nanoscale sensitivity for characterizing SMMs under realistic conditions relevant to their use as surface-bound memory units.
format Preprint
id arxiv_https___arxiv_org_abs_2505_19207
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Sensing single molecule magnets with nitrogen vacancy centers
Smooha, Ariel
Kumar, Jitender
Yudilevich, Dan
Rosenberg, John W.
Bayer, Valentin
Stöhr, Rainer
Denisenko, Andrej
Bendikov, Tatyana
Kossoy, Anna
Pinkas, Iddo
Tan, Hengxin
Yan, Binghai
Sarjar, Biprajit
van Slageren, Joris
Finkler, Amit
Quantum Physics
Single-molecule magnets (SMMs) are molecules that can function as nanoscale magnets with potential use as magnetic memory bits. While SMMs can retain magnetization at low temperatures, characterizing them on surface and at room temperature remains challenging and requires specialized nanoscale techniques. Here, we use single nitrogen-vacancy (NV) centers in diamond as highly sensitive, broadband magnetic field sensors to detect the magnetic noise of cobalt-based SMMs deposited on a diamond surface. We measure the NV relaxation and decoherence times at 296 K and at 5-8 K, observing a significant influence of the SMMs on them. From this, we can infer the SMMs' magnetic noise spectral density (NSD) and underlying magnetic properties. Moreover, we observe the effect of an applied magnetic field on the SMMs' NSD at low temperatures. The method provides nanoscale sensitivity for characterizing SMMs under realistic conditions relevant to their use as surface-bound memory units.
title Sensing single molecule magnets with nitrogen vacancy centers
topic Quantum Physics
url https://arxiv.org/abs/2505.19207