Nano-Raman Spectroscopy Analysis of Nanoprotuberances in MoSe2

Fuente: arXiv
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Main Authors: Guimarães, Jane Elisa, Nadas, Rafael, Alves, Rayan, Zhang, Wenjin, Endo, Takahiko, Watanabe, Kenji, Taniguchi, Takashi, Saito, Riichiro, Miyata, Yasumitsu, Neves, Bernardo R. A., Jorio, Ado
Format: Preprint
Published: 2025
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author Guimarães, Jane Elisa
Nadas, Rafael
Alves, Rayan
Zhang, Wenjin
Endo, Takahiko
Watanabe, Kenji
Taniguchi, Takashi
Saito, Riichiro
Miyata, Yasumitsu
Neves, Bernardo R. A.
Jorio, Ado
author_facet Guimarães, Jane Elisa
Nadas, Rafael
Alves, Rayan
Zhang, Wenjin
Endo, Takahiko
Watanabe, Kenji
Taniguchi, Takashi
Saito, Riichiro
Miyata, Yasumitsu
Neves, Bernardo R. A.
Jorio, Ado
contents Contaminations in the formation of two-dimensional heterostructures can hinder or generate desired properties. Recent advancements have highlighted the potential of tip-enhanced Raman spectroscopy (TERS) for studying materials in the 2D semiconductor class. In this work, we investigate the influence of 50-200nm sized nanoprotuberances within a monolayer of MoSe$_2$ deposited on hBN using nano-Raman spectroscopy, establishing correlations between the presence of localized contaminations and the observed hyperspectral variations. A figure of merit is established for the identification of surface impurities, based on MoSe$_2$ peaks ratio. Notably, new spectral peaks were identified, which are associated with the presence of nanoprotuberances and may indicate contamination and oxidation.
format Preprint
id arxiv_https___arxiv_org_abs_2505_19224
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Nano-Raman Spectroscopy Analysis of Nanoprotuberances in MoSe2
Guimarães, Jane Elisa
Nadas, Rafael
Alves, Rayan
Zhang, Wenjin
Endo, Takahiko
Watanabe, Kenji
Taniguchi, Takashi
Saito, Riichiro
Miyata, Yasumitsu
Neves, Bernardo R. A.
Jorio, Ado
Optics
Contaminations in the formation of two-dimensional heterostructures can hinder or generate desired properties. Recent advancements have highlighted the potential of tip-enhanced Raman spectroscopy (TERS) for studying materials in the 2D semiconductor class. In this work, we investigate the influence of 50-200nm sized nanoprotuberances within a monolayer of MoSe$_2$ deposited on hBN using nano-Raman spectroscopy, establishing correlations between the presence of localized contaminations and the observed hyperspectral variations. A figure of merit is established for the identification of surface impurities, based on MoSe$_2$ peaks ratio. Notably, new spectral peaks were identified, which are associated with the presence of nanoprotuberances and may indicate contamination and oxidation.
title Nano-Raman Spectroscopy Analysis of Nanoprotuberances in MoSe2
topic Optics
url https://arxiv.org/abs/2505.19224