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| Main Authors: | , , |
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| Format: | Preprint |
| Published: |
2025
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| Subjects: | |
| Online Access: | https://arxiv.org/abs/2505.19444 |
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| _version_ | 1866909623031693312 |
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| author | Inoue, Soshun Inaoka, Takeshi Ishihara, Hajime |
| author_facet | Inoue, Soshun Inaoka, Takeshi Ishihara, Hajime |
| contents | Hot carrier generation in metals, where high-energy electron-hole pairs are produced via plasmon excitation,
has emerged as a promising mechanism for photoelectric conversion and photocatalysis. However, conventional
theories often describe this process through phenomenological relaxation via Landau damping, which fails to
account for the microscopic origin of the frequency-dependent internal quantum efficiency (IQE) observed in
experiments. To address this gap, we develop an extended Bohm-Pines theory for a metallic thin film that
explicitly incorporates light-matter interactions within a non-local response framework. Our approach treats
collective (plasmonic) and individual (electron-hole) excitations on equal footing and includes their coupling
mediated by both longitudinal and transverse electromagnetic fields. This results in a self-consistent theory
of the optical response of metallic films. The derived total Hamiltonian includes radiative corrections that
recover the known dispersion of surface plasmon polaritons and, importantly, predict a frequency-dependent
radiative coupling between collective and individual modes. This previously neglected transverse coupling
naturally explains the IQE peak near the plasmon resonance and reveals a new mechanism of hot carrier
generation distinct from conventional Landau damping. Our results provide a unified theoretical foundation for
understanding plasmon-induced hot carrier dynamics and offer guidance for resonance-based photonic design
strategies to enhance energy conversion efficiency in metal nanostructures. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2505_19444 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Radiative coupling between plasmon and electron-hole pairs in a metallic film based on extended Bohm-Pines theory Inoue, Soshun Inaoka, Takeshi Ishihara, Hajime Optics Hot carrier generation in metals, where high-energy electron-hole pairs are produced via plasmon excitation, has emerged as a promising mechanism for photoelectric conversion and photocatalysis. However, conventional theories often describe this process through phenomenological relaxation via Landau damping, which fails to account for the microscopic origin of the frequency-dependent internal quantum efficiency (IQE) observed in experiments. To address this gap, we develop an extended Bohm-Pines theory for a metallic thin film that explicitly incorporates light-matter interactions within a non-local response framework. Our approach treats collective (plasmonic) and individual (electron-hole) excitations on equal footing and includes their coupling mediated by both longitudinal and transverse electromagnetic fields. This results in a self-consistent theory of the optical response of metallic films. The derived total Hamiltonian includes radiative corrections that recover the known dispersion of surface plasmon polaritons and, importantly, predict a frequency-dependent radiative coupling between collective and individual modes. This previously neglected transverse coupling naturally explains the IQE peak near the plasmon resonance and reveals a new mechanism of hot carrier generation distinct from conventional Landau damping. Our results provide a unified theoretical foundation for understanding plasmon-induced hot carrier dynamics and offer guidance for resonance-based photonic design strategies to enhance energy conversion efficiency in metal nanostructures. |
| title | Radiative coupling between plasmon and electron-hole pairs in a metallic film based on extended Bohm-Pines theory |
| topic | Optics |
| url | https://arxiv.org/abs/2505.19444 |