Diverse edge states of nanoribbons and excitonic insulator states of the monolayer Ta2Ni3Te5

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Hauptverfasser: Tang, Hong, Wei, Jiang, Csonka, Gabor I., Ruzsinszky, Adrienn
Format: Preprint
Veröffentlicht: 2025
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author Tang, Hong
Wei, Jiang
Csonka, Gabor I.
Ruzsinszky, Adrienn
author_facet Tang, Hong
Wei, Jiang
Csonka, Gabor I.
Ruzsinszky, Adrienn
contents Ta2Ni3Te5, a layered transition metal chalcogenide with quasi-one-dimensional electronic states, exhibits rich topological and correlated phenomena. Using first-principles calculations, we explore Ta2Ni3Te5 nanoribbons, demonstrating tunable electronic and magnetic properties-ranging from metallic to semimetallic and semiconducting (band gaps of 29.7-60.8 meV), and from ferromagnetic to antiferromagnetic-controlled by edge (Ni or Ta), ribbon width, and H/F saturation. Additionally, GW and Bethe-Salpeter equation (BSE) calculations, complemented by metaGGA-based modified BSE, reveal that the Ta2Ni3Te5 monolayer is an excitonic insulator, with an exciton binding energy exceeding its band gap. These diverse properties position Ta2Ni3Te5 nanoribbons and monolayers as promising candidates for nanoelectronics, spintronics, and optoelectronics, motivating further experimental exploration.
format Preprint
id arxiv_https___arxiv_org_abs_2505_22955
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Diverse edge states of nanoribbons and excitonic insulator states of the monolayer Ta2Ni3Te5
Tang, Hong
Wei, Jiang
Csonka, Gabor I.
Ruzsinszky, Adrienn
Materials Science
Mesoscale and Nanoscale Physics
Computational Physics
Ta2Ni3Te5, a layered transition metal chalcogenide with quasi-one-dimensional electronic states, exhibits rich topological and correlated phenomena. Using first-principles calculations, we explore Ta2Ni3Te5 nanoribbons, demonstrating tunable electronic and magnetic properties-ranging from metallic to semimetallic and semiconducting (band gaps of 29.7-60.8 meV), and from ferromagnetic to antiferromagnetic-controlled by edge (Ni or Ta), ribbon width, and H/F saturation. Additionally, GW and Bethe-Salpeter equation (BSE) calculations, complemented by metaGGA-based modified BSE, reveal that the Ta2Ni3Te5 monolayer is an excitonic insulator, with an exciton binding energy exceeding its band gap. These diverse properties position Ta2Ni3Te5 nanoribbons and monolayers as promising candidates for nanoelectronics, spintronics, and optoelectronics, motivating further experimental exploration.
title Diverse edge states of nanoribbons and excitonic insulator states of the monolayer Ta2Ni3Te5
topic Materials Science
Mesoscale and Nanoscale Physics
Computational Physics
url https://arxiv.org/abs/2505.22955