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Autori principali: Goto, Daiki, Kuga, Kentaro, Tanaka, Kiyohisa, Takeuchi, Tsunehiro, Matsunami, Masaharu
Natura: Preprint
Pubblicazione: 2025
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Accesso online:https://arxiv.org/abs/2505.24192
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author Goto, Daiki
Kuga, Kentaro
Tanaka, Kiyohisa
Takeuchi, Tsunehiro
Matsunami, Masaharu
author_facet Goto, Daiki
Kuga, Kentaro
Tanaka, Kiyohisa
Takeuchi, Tsunehiro
Matsunami, Masaharu
contents In the field of thermoelectric materials and devices, improving energy conversion efficiency remains a long-standing challenge. As a promising approach to address this issue, utilizing energy-dependent electron-scattering beyond the ordinary constant relaxation time approximation (CRTA) has been proposed. However, direct experimental evidence for an energy-dependent scattering reflected in the Seebeck coefficient is still lacking. Here we demonstrate using angle-resolved photoemission spectroscopy that the relaxation time of heavy fermion quasiparticles is highly dependent on the energy near the Fermi level. The observed energy dependence of the relaxation time is due to the coherent Kondo scattering, describing the sign of the Seebeck coefficient reasonably well, which cannot be deduced from CRTA. Our findings provide not only deeper insight into the understanding of thermoelectricity in correlated materials, but also future perspectives on possible orbital-selective engineering of thermoelectric materials.
format Preprint
id arxiv_https___arxiv_org_abs_2505_24192
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Evidence for energy-dependent scattering dominating thermoelectricity in heavy fermion systems
Goto, Daiki
Kuga, Kentaro
Tanaka, Kiyohisa
Takeuchi, Tsunehiro
Matsunami, Masaharu
Strongly Correlated Electrons
Materials Science
In the field of thermoelectric materials and devices, improving energy conversion efficiency remains a long-standing challenge. As a promising approach to address this issue, utilizing energy-dependent electron-scattering beyond the ordinary constant relaxation time approximation (CRTA) has been proposed. However, direct experimental evidence for an energy-dependent scattering reflected in the Seebeck coefficient is still lacking. Here we demonstrate using angle-resolved photoemission spectroscopy that the relaxation time of heavy fermion quasiparticles is highly dependent on the energy near the Fermi level. The observed energy dependence of the relaxation time is due to the coherent Kondo scattering, describing the sign of the Seebeck coefficient reasonably well, which cannot be deduced from CRTA. Our findings provide not only deeper insight into the understanding of thermoelectricity in correlated materials, but also future perspectives on possible orbital-selective engineering of thermoelectric materials.
title Evidence for energy-dependent scattering dominating thermoelectricity in heavy fermion systems
topic Strongly Correlated Electrons
Materials Science
url https://arxiv.org/abs/2505.24192