Nanoelectrospray ionization coupled to a linear charge detection array ion trap spectrometer for single viral particles analysis

Fuente: arXiv
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Autores principales: Maclot, S., Reinert, T., Duplantier, L., Montagne, G., Clavier, C., Dagany, X., Comby-Zerbino, C., Kerleroux, M., Thiede, L., Pogan, R., Uetrecht, C., Kozhinov, A. N., Nagornov, K. O., Tsybin, Y. O., Papanastasiou, D., Antoine, R.
Formato: Preprint
Publicado: 2025
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author Maclot, S.
Reinert, T.
Duplantier, L.
Montagne, G.
Clavier, C.
Dagany, X.
Comby-Zerbino, C.
Kerleroux, M.
Thiede, L.
Pogan, R.
Uetrecht, C.
Kozhinov, A. N.
Nagornov, K. O.
Tsybin, Y. O.
Papanastasiou, D.
Antoine, R.
author_facet Maclot, S.
Reinert, T.
Duplantier, L.
Montagne, G.
Clavier, C.
Dagany, X.
Comby-Zerbino, C.
Kerleroux, M.
Thiede, L.
Pogan, R.
Uetrecht, C.
Kozhinov, A. N.
Nagornov, K. O.
Tsybin, Y. O.
Papanastasiou, D.
Antoine, R.
contents This work presents the implementation of a new charge detection mass spectrometer (CDMS) design that operates in a stand-alone mode, thanks to its integration with nanoelectrospray ionization. More specifically, this innovative CDMS consists of a linear charge detection array ion trap spectrometer that combines an eight-tube detector array with conical electrodes. This configuration allows for recording data in both transmission mode (linear array) and ion trapping mode (ConeArrayTrap), which enables the measurement of time-of-flight (related to the mass-to-charge ratio) along with the charge of individual ions. As a result, this design supports high-throughput metrology of viruses at the single-particle level. The devices and geometry of the instrument have been developed based on ion optics simulations. The performance of the current instrument is demonstrated using human norovirus-like particles (hNoVLP) and Adenovirus Ad(5) (hAdV5).
format Preprint
id arxiv_https___arxiv_org_abs_2506_01593
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Nanoelectrospray ionization coupled to a linear charge detection array ion trap spectrometer for single viral particles analysis
Maclot, S.
Reinert, T.
Duplantier, L.
Montagne, G.
Clavier, C.
Dagany, X.
Comby-Zerbino, C.
Kerleroux, M.
Thiede, L.
Pogan, R.
Uetrecht, C.
Kozhinov, A. N.
Nagornov, K. O.
Tsybin, Y. O.
Papanastasiou, D.
Antoine, R.
Instrumentation and Detectors
Biological Physics
Chemical Physics
This work presents the implementation of a new charge detection mass spectrometer (CDMS) design that operates in a stand-alone mode, thanks to its integration with nanoelectrospray ionization. More specifically, this innovative CDMS consists of a linear charge detection array ion trap spectrometer that combines an eight-tube detector array with conical electrodes. This configuration allows for recording data in both transmission mode (linear array) and ion trapping mode (ConeArrayTrap), which enables the measurement of time-of-flight (related to the mass-to-charge ratio) along with the charge of individual ions. As a result, this design supports high-throughput metrology of viruses at the single-particle level. The devices and geometry of the instrument have been developed based on ion optics simulations. The performance of the current instrument is demonstrated using human norovirus-like particles (hNoVLP) and Adenovirus Ad(5) (hAdV5).
title Nanoelectrospray ionization coupled to a linear charge detection array ion trap spectrometer for single viral particles analysis
topic Instrumentation and Detectors
Biological Physics
Chemical Physics
url https://arxiv.org/abs/2506.01593