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Autores principales: Lee, Ka Yin, Beutler, Elliot K., Crisolo, Tifany Q., Masiello, David J., Lagos, Maureen J.
Formato: Preprint
Publicado: 2025
Materias:
Acceso en línea:https://arxiv.org/abs/2506.04395
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author Lee, Ka Yin
Beutler, Elliot K.
Crisolo, Tifany Q.
Masiello, David J.
Lagos, Maureen J.
author_facet Lee, Ka Yin
Beutler, Elliot K.
Crisolo, Tifany Q.
Masiello, David J.
Lagos, Maureen J.
contents Using vibrational electron energy loss spectroscopy (vib-EELS) combined with numerical modeling, we investigate the physical mechanisms governing the phonon coupling between a spherical particle sustaining multipolar surface phonon modes and an underlying thin film. Depending upon their dielectric composition, a variety of hybrid phonon modes arise in the EEL spectrum due to the interaction between polarization charges in the particle and film. Mirror charge effects and phonon mode hybridization are the active mechanisms acting on dielectric and metallic-type films, respectively. Processes beyond dipole-dipole interactions are required to describe the sphere-film coupling.
format Preprint
id arxiv_https___arxiv_org_abs_2506_04395
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Substrate matters: Coupled phonon modes of a spherical particle on a substrate probed with EELS
Lee, Ka Yin
Beutler, Elliot K.
Crisolo, Tifany Q.
Masiello, David J.
Lagos, Maureen J.
Materials Science
Using vibrational electron energy loss spectroscopy (vib-EELS) combined with numerical modeling, we investigate the physical mechanisms governing the phonon coupling between a spherical particle sustaining multipolar surface phonon modes and an underlying thin film. Depending upon their dielectric composition, a variety of hybrid phonon modes arise in the EEL spectrum due to the interaction between polarization charges in the particle and film. Mirror charge effects and phonon mode hybridization are the active mechanisms acting on dielectric and metallic-type films, respectively. Processes beyond dipole-dipole interactions are required to describe the sphere-film coupling.
title Substrate matters: Coupled phonon modes of a spherical particle on a substrate probed with EELS
topic Materials Science
url https://arxiv.org/abs/2506.04395