Sulfur in Hydrothermal Fluids

Fuente: arXiv
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Auteurs principaux: Pokrovski, Gleb S., Kouzmanov, Kalin, Andri, Stefansson
Format: Preprint
Publié: 2025
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author Pokrovski, Gleb S.
Kouzmanov, Kalin
Andri, Stefansson
author_facet Pokrovski, Gleb S.
Kouzmanov, Kalin
Andri, Stefansson
contents This chapter overviews sulfur chemical speciation and behavior in different types of hydrothermal fluids across the lithosphere, spanning from active geothermal systems to basinal brines, to metamorphic and magmatic-hydrothermal fluids. The information on sulfur in these fluids stems from a wide range of recent analytical, experimental and computational methods whose advantages and limitations are discussed. A special emphasis is given to in situ approaches that have enabled unprecedented insights into the fascinating sulfur chemistry in hydrothermal fluids. These insights motivated a critical review of the chemical speciation of key base, precious, and critical metals whose behavior is intimately linked to sulfur. The results allow the role played by the different sulfur ligands on hydrothermal transport of metals and ore deposit formation to be evaluated. An outline of major challenges and emerging perspectives for sulfur-related research in geological fluids ends up this chapter.
format Preprint
id arxiv_https___arxiv_org_abs_2506_05845
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Sulfur in Hydrothermal Fluids
Pokrovski, Gleb S.
Kouzmanov, Kalin
Andri, Stefansson
Chemical Physics
This chapter overviews sulfur chemical speciation and behavior in different types of hydrothermal fluids across the lithosphere, spanning from active geothermal systems to basinal brines, to metamorphic and magmatic-hydrothermal fluids. The information on sulfur in these fluids stems from a wide range of recent analytical, experimental and computational methods whose advantages and limitations are discussed. A special emphasis is given to in situ approaches that have enabled unprecedented insights into the fascinating sulfur chemistry in hydrothermal fluids. These insights motivated a critical review of the chemical speciation of key base, precious, and critical metals whose behavior is intimately linked to sulfur. The results allow the role played by the different sulfur ligands on hydrothermal transport of metals and ore deposit formation to be evaluated. An outline of major challenges and emerging perspectives for sulfur-related research in geological fluids ends up this chapter.
title Sulfur in Hydrothermal Fluids
topic Chemical Physics
url https://arxiv.org/abs/2506.05845