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Main Authors: Elettivo, G. S., Ferraro, M., Filosa, R., Nicolino, A., Marmiroli, B., Turchet, A., Agostino, R. G.
Format: Preprint
Published: 2025
Subjects:
Online Access:https://arxiv.org/abs/2506.06289
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author Elettivo, G. S.
Ferraro, M.
Filosa, R.
Nicolino, A.
Marmiroli, B.
Turchet, A.
Agostino, R. G.
author_facet Elettivo, G. S.
Ferraro, M.
Filosa, R.
Nicolino, A.
Marmiroli, B.
Turchet, A.
Agostino, R. G.
contents Owing to its high brightness, synchrotron light allows for investigating with extreme precision the physical properties of matter. The irradiation with high-dose X-ray beams may also lead to modification of the latter, thus allowing for material processing. Here we investigate the color change of topaz irradiated with synchrotron light, shedding light on the role played by secondary electrons in the formation of color centers. As a matter of fact, treatments of natural topaz to induce its color change are largely used in the jewelry industry. Nevertheless, the physical mechanisms behind the topaz's color change have not yet been fully understood. To date, it has been shown that the combined action of high-energy beam irradiation (either electrons, neutrons, or γ-rays) and thermal annealing permits to provide colorless natural topaz with an artificial blue color, which is largely appealed in the gem market. Here we demonstrate that it is possible to irreversibly provide natural topaz with a blue color even by exploiting lower energy beams, such as X-rays, provided that enough dose is absorbed, thus paving the way for developing novel protocols for making artificially blue topazes.
format Preprint
id arxiv_https___arxiv_org_abs_2506_06289
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle On the role of secondary electrons in the color change of high-dose X-ray irradiated topaz
Elettivo, G. S.
Ferraro, M.
Filosa, R.
Nicolino, A.
Marmiroli, B.
Turchet, A.
Agostino, R. G.
Materials Science
Applied Physics
Owing to its high brightness, synchrotron light allows for investigating with extreme precision the physical properties of matter. The irradiation with high-dose X-ray beams may also lead to modification of the latter, thus allowing for material processing. Here we investigate the color change of topaz irradiated with synchrotron light, shedding light on the role played by secondary electrons in the formation of color centers. As a matter of fact, treatments of natural topaz to induce its color change are largely used in the jewelry industry. Nevertheless, the physical mechanisms behind the topaz's color change have not yet been fully understood. To date, it has been shown that the combined action of high-energy beam irradiation (either electrons, neutrons, or γ-rays) and thermal annealing permits to provide colorless natural topaz with an artificial blue color, which is largely appealed in the gem market. Here we demonstrate that it is possible to irreversibly provide natural topaz with a blue color even by exploiting lower energy beams, such as X-rays, provided that enough dose is absorbed, thus paving the way for developing novel protocols for making artificially blue topazes.
title On the role of secondary electrons in the color change of high-dose X-ray irradiated topaz
topic Materials Science
Applied Physics
url https://arxiv.org/abs/2506.06289