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Main Authors: Kengle, Caitlin S., Schnitzer, Noah, Peterson, Elizabeth A., Guo, Chunyu, Zhang, Ling, Cook, Matthew S., Zhu, Jian-Xin, Thomas, Sean M., Moll, Philip J. W., Ronning, Filip, Rosa, Priscila F. S.
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2506.09235
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author Kengle, Caitlin S.
Schnitzer, Noah
Peterson, Elizabeth A.
Guo, Chunyu
Zhang, Ling
Cook, Matthew S.
Zhu, Jian-Xin
Thomas, Sean M.
Moll, Philip J. W.
Ronning, Filip
Rosa, Priscila F. S.
author_facet Kengle, Caitlin S.
Schnitzer, Noah
Peterson, Elizabeth A.
Guo, Chunyu
Zhang, Ling
Cook, Matthew S.
Zhu, Jian-Xin
Thomas, Sean M.
Moll, Philip J. W.
Ronning, Filip
Rosa, Priscila F. S.
contents Excitonic insulators are electronically-driven phases of matter characterized by the spontaneous condensation of electron-hole pairs. Here we show that La$_3$Cd$_2$As$_6$ undergoes a transition at $T_{0}=278$ K to a highly insulating state with no accompanying structural transition. We observe quasi-two-dimensional electrical transport and charge fluctuations consistent with an electronic transition enabled by enhanced Coulomb interactions. Density functional theory calculations are unable to replicate the insulating ground state. Our results support the opening of a gap by excitonic effects at $T_{0}$, placing La$_3$Cd$_2$As$_6$ as a rare example of a bulk excitonic insulator.
format Preprint
id arxiv_https___arxiv_org_abs_2506_09235
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Putative excitonic insulating state in narrow-gap semiconductor La$_3$Cd$_2$As$_6$
Kengle, Caitlin S.
Schnitzer, Noah
Peterson, Elizabeth A.
Guo, Chunyu
Zhang, Ling
Cook, Matthew S.
Zhu, Jian-Xin
Thomas, Sean M.
Moll, Philip J. W.
Ronning, Filip
Rosa, Priscila F. S.
Strongly Correlated Electrons
Excitonic insulators are electronically-driven phases of matter characterized by the spontaneous condensation of electron-hole pairs. Here we show that La$_3$Cd$_2$As$_6$ undergoes a transition at $T_{0}=278$ K to a highly insulating state with no accompanying structural transition. We observe quasi-two-dimensional electrical transport and charge fluctuations consistent with an electronic transition enabled by enhanced Coulomb interactions. Density functional theory calculations are unable to replicate the insulating ground state. Our results support the opening of a gap by excitonic effects at $T_{0}$, placing La$_3$Cd$_2$As$_6$ as a rare example of a bulk excitonic insulator.
title Putative excitonic insulating state in narrow-gap semiconductor La$_3$Cd$_2$As$_6$
topic Strongly Correlated Electrons
url https://arxiv.org/abs/2506.09235