Improved H2-He and H2-H2 Collision-Induced Absorption Models and Application to Outer-Planet Atmospheres
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| Format: | Preprint |
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2025
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| _version_ | 1866915336816689152 |
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| author | Orton, Glenn S. Gustafsson, Magnus Fletcher, Leigh N. Roman, Michael T. Sinclair, James A. |
| author_facet | Orton, Glenn S. Gustafsson, Magnus Fletcher, Leigh N. Roman, Michael T. Sinclair, James A. |
| contents | Using state-of-the-art ab initio interaction-induced dipole and potential-energy surfaces for hydrogen-helium (H2-He) pairs, we compute the rototranslational collision-induced absorption coefficient at 40-400 K for frequencies covering 0-4000 cm-1. The quantum mechanical scattering calculations account for the full anisotropic interaction potential, replacing the isotropic approximation. The absorption data are expected to be accurate with an uncertainty of 2% or better up to 2500 cm-1. The uncertainty is slightly higher at the highest frequencies where the rototranslational absorption is largely obscured by the rovibrational band. Our improved agreement with measurements at 200-800 cm-1 results from the improvement of the potential energy surface. The previously available rototranslational data set for H2-H2 pairs (Fletcher et al., Astrophys. J. Supp. 235, 24 (2018)) is also extended up to 4000 cm-1. In the rovibrational band previous isotropic potential calculations for H2-He (Gustafsson et al. J. Chem. Physics. 113, 3641 (2000)) and H2-H2 (Borysow, Icarus 92, 273 (1992)) have been extended to complement the rototranslational data set. The absorption coefficients are tabulated for ortho-to-para ratios from normal-H2 to pure para-H2, as well as equilibrium-H2, over 40-400 K. The effect of these updates are simulated for the cold atmosphere of Uranus and warmer atmosphere of Jupiter. They are equivalent to a brightness temperature difference of a fraction of a degree in the rototranslational region but up to 4 degrees in the rovibrational region. Our state-of-the-art modifications correct an otherwise +2% error in determining the He/H2 ratio in Uranus from its spectrum alone. |
| format | Preprint |
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arxiv_https___arxiv_org_abs_2506_09257 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Improved H2-He and H2-H2 Collision-Induced Absorption Models and Application to Outer-Planet Atmospheres Orton, Glenn S. Gustafsson, Magnus Fletcher, Leigh N. Roman, Michael T. Sinclair, James A. Earth and Planetary Astrophysics Chemical Physics Using state-of-the-art ab initio interaction-induced dipole and potential-energy surfaces for hydrogen-helium (H2-He) pairs, we compute the rototranslational collision-induced absorption coefficient at 40-400 K for frequencies covering 0-4000 cm-1. The quantum mechanical scattering calculations account for the full anisotropic interaction potential, replacing the isotropic approximation. The absorption data are expected to be accurate with an uncertainty of 2% or better up to 2500 cm-1. The uncertainty is slightly higher at the highest frequencies where the rototranslational absorption is largely obscured by the rovibrational band. Our improved agreement with measurements at 200-800 cm-1 results from the improvement of the potential energy surface. The previously available rototranslational data set for H2-H2 pairs (Fletcher et al., Astrophys. J. Supp. 235, 24 (2018)) is also extended up to 4000 cm-1. In the rovibrational band previous isotropic potential calculations for H2-He (Gustafsson et al. J. Chem. Physics. 113, 3641 (2000)) and H2-H2 (Borysow, Icarus 92, 273 (1992)) have been extended to complement the rototranslational data set. The absorption coefficients are tabulated for ortho-to-para ratios from normal-H2 to pure para-H2, as well as equilibrium-H2, over 40-400 K. The effect of these updates are simulated for the cold atmosphere of Uranus and warmer atmosphere of Jupiter. They are equivalent to a brightness temperature difference of a fraction of a degree in the rototranslational region but up to 4 degrees in the rovibrational region. Our state-of-the-art modifications correct an otherwise +2% error in determining the He/H2 ratio in Uranus from its spectrum alone. |
| title | Improved H2-He and H2-H2 Collision-Induced Absorption Models and Application to Outer-Planet Atmospheres |
| topic | Earth and Planetary Astrophysics Chemical Physics |
| url | https://arxiv.org/abs/2506.09257 |