Re-analysis of 10 Hot-Jupiter Atmospheres with disequilibrium chemistry retrieval

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Main Authors: Bardet, Deborah, Changeat, Quentin, Venot, Olivia, Panek, Emilie
Format: Preprint
Published: 2025
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author Bardet, Deborah
Changeat, Quentin
Venot, Olivia
Panek, Emilie
author_facet Bardet, Deborah
Changeat, Quentin
Venot, Olivia
Panek, Emilie
contents Constraining the chemical structure of exoplanetary atmospheres is pivotal for interpreting spectroscopic data and understanding planetary evolution. Traditional retrieval methods often assume thermochemical equilibrium or free profiles, which may fail to capture disequilibrium processes like photodissociation and vertical mixing. This study leverages the TauREx 3.1 retrieval framework coupled with FRECKLL, a disequilibrium chemistry model, to address these challenges. The study aims to (1) assess the impact of disequilibrium chemistry on constraining metallicity and C/O ratios; (2) evaluate the role of refractory species (TiO and VO) in spectral retrievals; (3) explore consistency between transit and eclipse observations for temperature and chemical profiles; and (4) determine the effects of retrieval priors and data reduction methods. Ten hot-Jupiter atmospheres were reanalyzed using Hubble Space Telescope (HST) WFC3 data in eclipse and transit. The TauREx-FRECKLL model incorporated disequilibrium chemistry calculations with a Bayesian framework to infer atmospheric properties. The disequilibrium approach significantly altered retrieved metallicity and C/O ratios compared to equilibrium models, impacting planet formation insights. Retrievals reconciled transit and eclipse temperature profiles in deeper atmospheric layers but not in upper layers. Results were highly dependent on spectral resolution and retrieval priors, emphasizing limitations of HST data and the need for broader spectral coverage from instruments like JWST. This study demonstrates the feasibility and importance of incorporating disequilibrium chemistry in atmospheric retrievals, highlighting its potential for advancing our understanding of exoplanetary atmospheres with next-generation telescopes.
format Preprint
id arxiv_https___arxiv_org_abs_2506_12806
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Re-analysis of 10 Hot-Jupiter Atmospheres with disequilibrium chemistry retrieval
Bardet, Deborah
Changeat, Quentin
Venot, Olivia
Panek, Emilie
Earth and Planetary Astrophysics
Constraining the chemical structure of exoplanetary atmospheres is pivotal for interpreting spectroscopic data and understanding planetary evolution. Traditional retrieval methods often assume thermochemical equilibrium or free profiles, which may fail to capture disequilibrium processes like photodissociation and vertical mixing. This study leverages the TauREx 3.1 retrieval framework coupled with FRECKLL, a disequilibrium chemistry model, to address these challenges. The study aims to (1) assess the impact of disequilibrium chemistry on constraining metallicity and C/O ratios; (2) evaluate the role of refractory species (TiO and VO) in spectral retrievals; (3) explore consistency between transit and eclipse observations for temperature and chemical profiles; and (4) determine the effects of retrieval priors and data reduction methods. Ten hot-Jupiter atmospheres were reanalyzed using Hubble Space Telescope (HST) WFC3 data in eclipse and transit. The TauREx-FRECKLL model incorporated disequilibrium chemistry calculations with a Bayesian framework to infer atmospheric properties. The disequilibrium approach significantly altered retrieved metallicity and C/O ratios compared to equilibrium models, impacting planet formation insights. Retrievals reconciled transit and eclipse temperature profiles in deeper atmospheric layers but not in upper layers. Results were highly dependent on spectral resolution and retrieval priors, emphasizing limitations of HST data and the need for broader spectral coverage from instruments like JWST. This study demonstrates the feasibility and importance of incorporating disequilibrium chemistry in atmospheric retrievals, highlighting its potential for advancing our understanding of exoplanetary atmospheres with next-generation telescopes.
title Re-analysis of 10 Hot-Jupiter Atmospheres with disequilibrium chemistry retrieval
topic Earth and Planetary Astrophysics
url https://arxiv.org/abs/2506.12806