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Main Authors: Osada, Motoki, Terakura, Chieko, Kikkawa, Akiko, Nakajima, Masamichi, Chen, Hsiao-Yi, Nomura, Yusuke, Tokura, Yoshinori, Tsukazaki, Atsushi
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2506.15319
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author Osada, Motoki
Terakura, Chieko
Kikkawa, Akiko
Nakajima, Masamichi
Chen, Hsiao-Yi
Nomura, Yusuke
Tokura, Yoshinori
Tsukazaki, Atsushi
author_facet Osada, Motoki
Terakura, Chieko
Kikkawa, Akiko
Nakajima, Masamichi
Chen, Hsiao-Yi
Nomura, Yusuke
Tokura, Yoshinori
Tsukazaki, Atsushi
contents The recent discovery of high-transition temperature ($T_\mathrm{c}$) superconductivity in pressurized La$_{3}$Ni$_{2}$O$_{7}$ bulk crystals has attracted keen attention due to its characteristic energy diagram of $e_{g}$ orbitals, containing nearly half-filled $d_{3z^2 - r^2}$ and quarter-filled $d_{x^2 - y^2}$ orbitals. This finding provides valuable insights into the orbital contributions and interlayer interactions in double NiO$_{6}$ octahedra, offering opportunities to control the electronic structure via ligand field variations. Here, we demonstrate strain-tuning of $T_\mathrm{c}$ over a range of 50 K in La$_{3}$Ni$_{2}$O$_{7}$ films grown on different oxide substrates under 20 GPa. As the $c/a$ ratio increases, the onset $T_\mathrm{c}$ systematically rises from 10 K in the tensile-strained film on SrTiO$_{3}$ to a maximum of about 60 K in the compressively strained film on LaAlO$_{3}$. These systematic variations suggest that strain engineering is a promising strategy for expanding superconductivity in bilayer nickelates by tuning the orbital energy landscape toward high-$T_\mathrm{c}$ superconductivity.
format Preprint
id arxiv_https___arxiv_org_abs_2506_15319
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Strain-tuning for superconductivity in La$_3$Ni$_2$O$_7$ thin films
Osada, Motoki
Terakura, Chieko
Kikkawa, Akiko
Nakajima, Masamichi
Chen, Hsiao-Yi
Nomura, Yusuke
Tokura, Yoshinori
Tsukazaki, Atsushi
Superconductivity
Materials Science
The recent discovery of high-transition temperature ($T_\mathrm{c}$) superconductivity in pressurized La$_{3}$Ni$_{2}$O$_{7}$ bulk crystals has attracted keen attention due to its characteristic energy diagram of $e_{g}$ orbitals, containing nearly half-filled $d_{3z^2 - r^2}$ and quarter-filled $d_{x^2 - y^2}$ orbitals. This finding provides valuable insights into the orbital contributions and interlayer interactions in double NiO$_{6}$ octahedra, offering opportunities to control the electronic structure via ligand field variations. Here, we demonstrate strain-tuning of $T_\mathrm{c}$ over a range of 50 K in La$_{3}$Ni$_{2}$O$_{7}$ films grown on different oxide substrates under 20 GPa. As the $c/a$ ratio increases, the onset $T_\mathrm{c}$ systematically rises from 10 K in the tensile-strained film on SrTiO$_{3}$ to a maximum of about 60 K in the compressively strained film on LaAlO$_{3}$. These systematic variations suggest that strain engineering is a promising strategy for expanding superconductivity in bilayer nickelates by tuning the orbital energy landscape toward high-$T_\mathrm{c}$ superconductivity.
title Strain-tuning for superconductivity in La$_3$Ni$_2$O$_7$ thin films
topic Superconductivity
Materials Science
url https://arxiv.org/abs/2506.15319