Space Group Symmetry of Chiral Fe-deficient van der Waals Magnet $\text{Fe}_{\text{3-x}}\text{GeTe}_{\text{2}}$ Probed by Convergent Beam Electron Diffraction

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Main Authors: Zaiets, O., Subakti, S., Wolf, D., Steinweh, J., Parkin, S., Lubk, A.
Format: Preprint
Published: 2025
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author Zaiets, O.
Subakti, S.
Wolf, D.
Steinweh, J.
Parkin, S.
Lubk, A.
author_facet Zaiets, O.
Subakti, S.
Wolf, D.
Steinweh, J.
Parkin, S.
Lubk, A.
contents The crystal symmetry of Fe-deficient $\text{Fe}_{\text{3-x}}\text{GeTe}_{\text{2}}$ at room temperature has been investigated by a combination of selected-area electron diffraction (SAED) and convergent-beam electron diffraction (CBED). By symmetry analysis of CBED patterns along different zone axis, the space group of $\text{Fe}_{\text{3-x}}\text{GeTe}_{\text{2}}$ at room-temperature has been identified as $P6_3mc$ (No.186), which derives from the high-symmetry parent system $\text{Fe}_{\text{3}}\text{GeTe}_{\text{2}}$ ($P6_3/mmc$) by breaking the mirror symmetry along the 6-fold rotation axis. The $P3m1$ (No.156) space group previously reported for $\text{Fe}_{\text{3-x}}\text{GeTe}_{\text{2}}$ is a subgroup of $P6_3mc$ suggesting further possible symmetry breaks in this non-stoichiometric system.
format Preprint
id arxiv_https___arxiv_org_abs_2506_16944
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Space Group Symmetry of Chiral Fe-deficient van der Waals Magnet $\text{Fe}_{\text{3-x}}\text{GeTe}_{\text{2}}$ Probed by Convergent Beam Electron Diffraction
Zaiets, O.
Subakti, S.
Wolf, D.
Steinweh, J.
Parkin, S.
Lubk, A.
Mesoscale and Nanoscale Physics
The crystal symmetry of Fe-deficient $\text{Fe}_{\text{3-x}}\text{GeTe}_{\text{2}}$ at room temperature has been investigated by a combination of selected-area electron diffraction (SAED) and convergent-beam electron diffraction (CBED). By symmetry analysis of CBED patterns along different zone axis, the space group of $\text{Fe}_{\text{3-x}}\text{GeTe}_{\text{2}}$ at room-temperature has been identified as $P6_3mc$ (No.186), which derives from the high-symmetry parent system $\text{Fe}_{\text{3}}\text{GeTe}_{\text{2}}$ ($P6_3/mmc$) by breaking the mirror symmetry along the 6-fold rotation axis. The $P3m1$ (No.156) space group previously reported for $\text{Fe}_{\text{3-x}}\text{GeTe}_{\text{2}}$ is a subgroup of $P6_3mc$ suggesting further possible symmetry breaks in this non-stoichiometric system.
title Space Group Symmetry of Chiral Fe-deficient van der Waals Magnet $\text{Fe}_{\text{3-x}}\text{GeTe}_{\text{2}}$ Probed by Convergent Beam Electron Diffraction
topic Mesoscale and Nanoscale Physics
url https://arxiv.org/abs/2506.16944