From the dynamic to the static glass transition via hypersonic measurements using Brillouin spectroscopy

Fuente: arXiv
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Autori principali: Krüger, Jan-Kristian, Riobóo, Rafael J. Jiménez, Wetzel, Bernd, Klingler, Andreas
Natura: Preprint
Pubblicazione: 2025
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author Krüger, Jan-Kristian
Riobóo, Rafael J. Jiménez
Wetzel, Bernd
Klingler, Andreas
author_facet Krüger, Jan-Kristian
Riobóo, Rafael J. Jiménez
Wetzel, Bernd
Klingler, Andreas
contents For the fragile, low-molecular-weight liquid diglycidyl ether of bisphenol A (DGEBA), we report on the dynamic glass transition and a further acoustic anomaly in the vicinity of the thermal glass transition based on hypersonic investigations of the longitudinal elastic modulus using Brillouin spectroscopy. This additional acoustic anomaly of the longitudinally polarized phonon is confirmed by the occurrence of an anomaly of the shear phonon at the same thermal glass transition temperature. Analysis of the generalized Cauchy relation suggests that both anomalies are coupled to a glass transition phenomenon independent of the so-called α-relaxation process.
format Preprint
id arxiv_https___arxiv_org_abs_2506_20808
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle From the dynamic to the static glass transition via hypersonic measurements using Brillouin spectroscopy
Krüger, Jan-Kristian
Riobóo, Rafael J. Jiménez
Wetzel, Bernd
Klingler, Andreas
Soft Condensed Matter
Materials Science
For the fragile, low-molecular-weight liquid diglycidyl ether of bisphenol A (DGEBA), we report on the dynamic glass transition and a further acoustic anomaly in the vicinity of the thermal glass transition based on hypersonic investigations of the longitudinal elastic modulus using Brillouin spectroscopy. This additional acoustic anomaly of the longitudinally polarized phonon is confirmed by the occurrence of an anomaly of the shear phonon at the same thermal glass transition temperature. Analysis of the generalized Cauchy relation suggests that both anomalies are coupled to a glass transition phenomenon independent of the so-called α-relaxation process.
title From the dynamic to the static glass transition via hypersonic measurements using Brillouin spectroscopy
topic Soft Condensed Matter
Materials Science
url https://arxiv.org/abs/2506.20808