Analytical Calculation of Viscosity in Rouse Networks Below Gelation Transition

Fuente: arXiv
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Autores principales: Lyu, Bohan, Lin, Jie
Formato: Preprint
Publicado: 2025
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author Lyu, Bohan
Lin, Jie
author_facet Lyu, Bohan
Lin, Jie
contents This work establishes an exact relationship between the zero-shear viscosity and the radius of gyration for generalized Rouse model with arbitrary network configurations. Building on this fundamental relationship, we develop a random graph approach to derive analytical expressions for network viscosity in mean-field connected systems through coarse-grained graph viscosity relations. The theory fully characterizes the subcritical regime, determining precise asymptotic behavior in both dilute and pre-gelation limits.
format Preprint
id arxiv_https___arxiv_org_abs_2506_21399
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Analytical Calculation of Viscosity in Rouse Networks Below Gelation Transition
Lyu, Bohan
Lin, Jie
Soft Condensed Matter
Chemical Physics
This work establishes an exact relationship between the zero-shear viscosity and the radius of gyration for generalized Rouse model with arbitrary network configurations. Building on this fundamental relationship, we develop a random graph approach to derive analytical expressions for network viscosity in mean-field connected systems through coarse-grained graph viscosity relations. The theory fully characterizes the subcritical regime, determining precise asymptotic behavior in both dilute and pre-gelation limits.
title Analytical Calculation of Viscosity in Rouse Networks Below Gelation Transition
topic Soft Condensed Matter
Chemical Physics
url https://arxiv.org/abs/2506.21399