Symmetry analysis of cross-circular and parallel-circular Raman optical activity

Fuente: arXiv
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Main Authors: Watanabe, Hikaru, Oiwa, Rikuto, Kusuno, Gakuto, Satoh, Takuya, Arita, Ryotaro
Format: Preprint
Published: 2025
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author Watanabe, Hikaru
Oiwa, Rikuto
Kusuno, Gakuto
Satoh, Takuya
Arita, Ryotaro
author_facet Watanabe, Hikaru
Oiwa, Rikuto
Kusuno, Gakuto
Satoh, Takuya
Arita, Ryotaro
contents The Raman scattering regarding the circularly-polarized incident and scattered lights is closely related to the circular activity of a given system. We investigate the symmetry of its activity, called the cross-circular and parallel-circular Raman optical activity. The analysis is systematically performed with the magnetic point groups and indicates that the response allows for a useful diagnosis of the symmetry of materials like chirality and (magneto-)axiality. It is also shown that the Stokes and anti-Stokes processes are related to each other by the conserved antiunitary symmetry for the time-reversal operation and that combined with the mirror reflection.
format Preprint
id arxiv_https___arxiv_org_abs_2506_21824
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Symmetry analysis of cross-circular and parallel-circular Raman optical activity
Watanabe, Hikaru
Oiwa, Rikuto
Kusuno, Gakuto
Satoh, Takuya
Arita, Ryotaro
Materials Science
The Raman scattering regarding the circularly-polarized incident and scattered lights is closely related to the circular activity of a given system. We investigate the symmetry of its activity, called the cross-circular and parallel-circular Raman optical activity. The analysis is systematically performed with the magnetic point groups and indicates that the response allows for a useful diagnosis of the symmetry of materials like chirality and (magneto-)axiality. It is also shown that the Stokes and anti-Stokes processes are related to each other by the conserved antiunitary symmetry for the time-reversal operation and that combined with the mirror reflection.
title Symmetry analysis of cross-circular and parallel-circular Raman optical activity
topic Materials Science
url https://arxiv.org/abs/2506.21824