A Thermodynamically Consistent Free Boundary Model for Two-Phase Flows in an Evolving Domain with Bulk-Surface Interaction

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Hauptverfasser: Knopf, Patrik, Liu, Yadong
Format: Preprint
Veröffentlicht: 2025
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author Knopf, Patrik
Liu, Yadong
author_facet Knopf, Patrik
Liu, Yadong
contents We derive a thermodynamically consistent model, which describes the time evolution of a two-phase flow in an evolving domain. The movement of the free boundary of the domain is driven by the velocity field of the mixture in the bulk, which is determined by a Navier--Stokes equation. In order to take interactions between bulk and boundary into account, we further consider two materials on the boundary, which may be the same or different materials as those in the bulk. The bulk and the surface materials are represented by respective phase-fields, whose time evolution is described by a bulk-surface convective Cahn--Hilliard equation. This approach allows for a transfer of material between bulk and surface as well as variable contact angles between the diffuse interface in the bulk and the boundary of the domain. To provide a more accurate description of the corresponding contact line motion, we include a generalized Navier slip boundary condition on the velocity field. Based on local mass balance laws, we derive our model from scratch in two different ways: by the Lagrange Multiplier Approach and (in the case of matched densities and no mass flux between bulk and surface) by the Energetic Variational Approach. We further show that our model generalizes previous models from the literature, which can be recovered from our system by either dropping the dynamic boundary conditions or assuming a static boundary of the domain.
format Preprint
id arxiv_https___arxiv_org_abs_2507_01618
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle A Thermodynamically Consistent Free Boundary Model for Two-Phase Flows in an Evolving Domain with Bulk-Surface Interaction
Knopf, Patrik
Liu, Yadong
Analysis of PDEs
Mathematical Physics
Fluid Dynamics
Primary: 76D27, Secondary: 35Q30, 35Q35, 35R35, 76D05, 76T06, 80A22
We derive a thermodynamically consistent model, which describes the time evolution of a two-phase flow in an evolving domain. The movement of the free boundary of the domain is driven by the velocity field of the mixture in the bulk, which is determined by a Navier--Stokes equation. In order to take interactions between bulk and boundary into account, we further consider two materials on the boundary, which may be the same or different materials as those in the bulk. The bulk and the surface materials are represented by respective phase-fields, whose time evolution is described by a bulk-surface convective Cahn--Hilliard equation. This approach allows for a transfer of material between bulk and surface as well as variable contact angles between the diffuse interface in the bulk and the boundary of the domain. To provide a more accurate description of the corresponding contact line motion, we include a generalized Navier slip boundary condition on the velocity field. Based on local mass balance laws, we derive our model from scratch in two different ways: by the Lagrange Multiplier Approach and (in the case of matched densities and no mass flux between bulk and surface) by the Energetic Variational Approach. We further show that our model generalizes previous models from the literature, which can be recovered from our system by either dropping the dynamic boundary conditions or assuming a static boundary of the domain.
title A Thermodynamically Consistent Free Boundary Model for Two-Phase Flows in an Evolving Domain with Bulk-Surface Interaction
topic Analysis of PDEs
Mathematical Physics
Fluid Dynamics
Primary: 76D27, Secondary: 35Q30, 35Q35, 35R35, 76D05, 76T06, 80A22
url https://arxiv.org/abs/2507.01618