Importance of anisotropic interactions for hard-axis/plane ordering of Ce-based ferromagnets

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Main Authors: Jin, Hanshang, Ullah, Rahim R., Klavins, Peter, Taufour, Valentin
Format: Preprint
Published: 2025
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author Jin, Hanshang
Ullah, Rahim R.
Klavins, Peter
Taufour, Valentin
author_facet Jin, Hanshang
Ullah, Rahim R.
Klavins, Peter
Taufour, Valentin
contents Ferromagnetic (FM) Kondo-lattice (KL) compounds often exhibit intriguing magnetic behavior driven by strong crystal electric field (CEF) anisotropy and exchange interactions. Recent studies suggest that many Ce-based and Yb-based KL ferromagnets order along the hard-axis or hard-plane determined by their CEF ground state. We performed a survey of Ce-based FM compounds, complemented with new single crystal synthesis, magnetization measurements, and analysis of the CEF scheme. Our results reveal that hard-axis/plane ordering is less common than previously reported, with most compounds ordering along their easy-axis/plane. We also find no clear correlation between the strength of the Kondo effect and whether a compound adopts hard-axis/plane or easy-axis/plane ordering. Instead, the key driver appears to be the competition between CEF anisotropy and exchange interaction anisotropy. A direct comparison of CeCuSi and CeAgSb$_2$ further indicates that antiferromagnetic (AFM) interactions along the CEF easy-axis can be crucial in stabilizing the hard-axis FM ordering observed in CeAgSb$_2$. Finally, our results suggest that an anisotropic Ruderman-Kittel-Kasuya-Yosida (RKKY) model could offer deeper insights into the complicated magnetic properties of Ce-based and other heavy-fermion systems.
format Preprint
id arxiv_https___arxiv_org_abs_2507_02615
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Importance of anisotropic interactions for hard-axis/plane ordering of Ce-based ferromagnets
Jin, Hanshang
Ullah, Rahim R.
Klavins, Peter
Taufour, Valentin
Strongly Correlated Electrons
Ferromagnetic (FM) Kondo-lattice (KL) compounds often exhibit intriguing magnetic behavior driven by strong crystal electric field (CEF) anisotropy and exchange interactions. Recent studies suggest that many Ce-based and Yb-based KL ferromagnets order along the hard-axis or hard-plane determined by their CEF ground state. We performed a survey of Ce-based FM compounds, complemented with new single crystal synthesis, magnetization measurements, and analysis of the CEF scheme. Our results reveal that hard-axis/plane ordering is less common than previously reported, with most compounds ordering along their easy-axis/plane. We also find no clear correlation between the strength of the Kondo effect and whether a compound adopts hard-axis/plane or easy-axis/plane ordering. Instead, the key driver appears to be the competition between CEF anisotropy and exchange interaction anisotropy. A direct comparison of CeCuSi and CeAgSb$_2$ further indicates that antiferromagnetic (AFM) interactions along the CEF easy-axis can be crucial in stabilizing the hard-axis FM ordering observed in CeAgSb$_2$. Finally, our results suggest that an anisotropic Ruderman-Kittel-Kasuya-Yosida (RKKY) model could offer deeper insights into the complicated magnetic properties of Ce-based and other heavy-fermion systems.
title Importance of anisotropic interactions for hard-axis/plane ordering of Ce-based ferromagnets
topic Strongly Correlated Electrons
url https://arxiv.org/abs/2507.02615