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Main Authors: Palkhivala, Shalom, Kohler, Larissa, Ritschel, Christian, Feldmann, Claus, Hunger, David
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2507.05236
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author Palkhivala, Shalom
Kohler, Larissa
Ritschel, Christian
Feldmann, Claus
Hunger, David
author_facet Palkhivala, Shalom
Kohler, Larissa
Ritschel, Christian
Feldmann, Claus
Hunger, David
contents Nanoparticles are ubiquitous, and methods that reveal insights into single-particle properties are highly desired to enable their advanced characterization. Techniques that achieve label-free single-nanoparticle detection often lack bandwidth or do not provide quantitative information. Here, we present a cavity-based dispersive sensing method that achieves a high bandwidth to capture all relevant timescales of translational diffusion, and a sensitivity to detect and size single particles with diameters down to 3 nm. We develop an analytical model describing the autocorrelation function for particle diffusion in a standing-wave sensing geometry and propose a method to address the challenges posed by the transient nature of single-particle signals. With this, we achieve quantitative particle sizing with high precision and accuracy, and provide an important tool to analyze single-particle diffusion.
format Preprint
id arxiv_https___arxiv_org_abs_2507_05236
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Accurate single-nanoparticle sizing down to 3 nm with an optofluidic microcavity
Palkhivala, Shalom
Kohler, Larissa
Ritschel, Christian
Feldmann, Claus
Hunger, David
Optics
Nanoparticles are ubiquitous, and methods that reveal insights into single-particle properties are highly desired to enable their advanced characterization. Techniques that achieve label-free single-nanoparticle detection often lack bandwidth or do not provide quantitative information. Here, we present a cavity-based dispersive sensing method that achieves a high bandwidth to capture all relevant timescales of translational diffusion, and a sensitivity to detect and size single particles with diameters down to 3 nm. We develop an analytical model describing the autocorrelation function for particle diffusion in a standing-wave sensing geometry and propose a method to address the challenges posed by the transient nature of single-particle signals. With this, we achieve quantitative particle sizing with high precision and accuracy, and provide an important tool to analyze single-particle diffusion.
title Accurate single-nanoparticle sizing down to 3 nm with an optofluidic microcavity
topic Optics
url https://arxiv.org/abs/2507.05236