Mass-transport-limited reaction rates and molecular diffusion in the van der Waals gap beneath graphene

Fuente: arXiv
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Main Authors: Mirdamadi, Hossein, David, Jiří, Wang, Rui, Jiang, Tianle, Wang, Yanming, Vařeka, Karel, Dymáček, Michal, Bábor, Petr, Šikola, Tomáš, Kolíbal, Miroslav
Format: Preprint
Published: 2025
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author Mirdamadi, Hossein
David, Jiří
Wang, Rui
Jiang, Tianle
Wang, Yanming
Vařeka, Karel
Dymáček, Michal
Bábor, Petr
Šikola, Tomáš
Kolíbal, Miroslav
author_facet Mirdamadi, Hossein
David, Jiří
Wang, Rui
Jiang, Tianle
Wang, Yanming
Vařeka, Karel
Dymáček, Michal
Bábor, Petr
Šikola, Tomáš
Kolíbal, Miroslav
contents The confinement of molecules within the van der Waals (vdW) gap between a two-dimensional 2D material and a catalytic substrate offers a promising route toward the development of molecule-selective catalysts with increased reaction rates. However, identifying the kinetic limitations of such confined reactions remains challenging. Here, we employ an inverted wedding-cake configuration of multilayer graphene on platinum to study the dynamics of graphene etching in the vdW gap by various molecules (O2, H2, and CO), using in situ scanning electron microscopy. Under the experimental conditions explored (up to p = 1.4x10-3 Pa and T = 1000 °C), the etching reaction rates are limited by mass transport within the confined space. This limitation persists even for CO, despite its anomalously enhanced transport resulting from a significant lifting of the vdW gap. Reactive molecular dynamics simulations further reveal multiple etching pathways for CO, enabled by confinement within the vdW space. Once mass-transport limitations are overcome, the vdW gap acts as an effective nanoreactor, facilitating reaction pathways that would be otherwise inaccessible on a pristine surface without spatial confinement.
format Preprint
id arxiv_https___arxiv_org_abs_2507_07479
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Mass-transport-limited reaction rates and molecular diffusion in the van der Waals gap beneath graphene
Mirdamadi, Hossein
David, Jiří
Wang, Rui
Jiang, Tianle
Wang, Yanming
Vařeka, Karel
Dymáček, Michal
Bábor, Petr
Šikola, Tomáš
Kolíbal, Miroslav
Mesoscale and Nanoscale Physics
The confinement of molecules within the van der Waals (vdW) gap between a two-dimensional 2D material and a catalytic substrate offers a promising route toward the development of molecule-selective catalysts with increased reaction rates. However, identifying the kinetic limitations of such confined reactions remains challenging. Here, we employ an inverted wedding-cake configuration of multilayer graphene on platinum to study the dynamics of graphene etching in the vdW gap by various molecules (O2, H2, and CO), using in situ scanning electron microscopy. Under the experimental conditions explored (up to p = 1.4x10-3 Pa and T = 1000 °C), the etching reaction rates are limited by mass transport within the confined space. This limitation persists even for CO, despite its anomalously enhanced transport resulting from a significant lifting of the vdW gap. Reactive molecular dynamics simulations further reveal multiple etching pathways for CO, enabled by confinement within the vdW space. Once mass-transport limitations are overcome, the vdW gap acts as an effective nanoreactor, facilitating reaction pathways that would be otherwise inaccessible on a pristine surface without spatial confinement.
title Mass-transport-limited reaction rates and molecular diffusion in the van der Waals gap beneath graphene
topic Mesoscale and Nanoscale Physics
url https://arxiv.org/abs/2507.07479