Interplay of polar order and positional order in liquid crystals -- observation of re-entrant ferroelectric nematic phase

Fuente: arXiv
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Autori principali: Strachan, Grant, Ramsay, Shona, Juodka, Marijus, Pociecha, Damian, Szydlowska, Jadwiga, Storey, John M. D., Vaupotic, Natasa, Walker, Rebecca, Gorecka, Ewa
Natura: Preprint
Pubblicazione: 2025
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author Strachan, Grant
Ramsay, Shona
Juodka, Marijus
Pociecha, Damian
Szydlowska, Jadwiga
Storey, John M. D.
Vaupotic, Natasa
Walker, Rebecca
Gorecka, Ewa
author_facet Strachan, Grant
Ramsay, Shona
Juodka, Marijus
Pociecha, Damian
Szydlowska, Jadwiga
Storey, John M. D.
Vaupotic, Natasa
Walker, Rebecca
Gorecka, Ewa
contents We show that development of polar order may spontaneously destroy the lamellar structure of a liquid crystal. This results in an unusual sequence of phases with the ferroelectric nematic phase appearing below a non-polar smectic phase. The effect is related to unfavourable dipole interactions within the smectic layers and can be explained by Landau theory in which the temperature dependent term is non-monotonic as it is renormalized by spontaneous electric polarization.
format Preprint
id arxiv_https___arxiv_org_abs_2507_08754
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Interplay of polar order and positional order in liquid crystals -- observation of re-entrant ferroelectric nematic phase
Strachan, Grant
Ramsay, Shona
Juodka, Marijus
Pociecha, Damian
Szydlowska, Jadwiga
Storey, John M. D.
Vaupotic, Natasa
Walker, Rebecca
Gorecka, Ewa
Soft Condensed Matter
We show that development of polar order may spontaneously destroy the lamellar structure of a liquid crystal. This results in an unusual sequence of phases with the ferroelectric nematic phase appearing below a non-polar smectic phase. The effect is related to unfavourable dipole interactions within the smectic layers and can be explained by Landau theory in which the temperature dependent term is non-monotonic as it is renormalized by spontaneous electric polarization.
title Interplay of polar order and positional order in liquid crystals -- observation of re-entrant ferroelectric nematic phase
topic Soft Condensed Matter
url https://arxiv.org/abs/2507.08754