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Main Authors: McClymont, William, Tacchella, Sandro, Smith, Aaron, Kannan, Rahul, Garaldi, Enrico, Puchwein, Ewald, Isobe, Yuki, Ji, Xihan, Shen, Xuejian, Wang, Zihao, Belokurov, Vasily, Borrow, Josh, D'Eugenio, Francesco, Keating, Laura, Maiolino, Roberto, Monty, Stephanie, Vogelsberger, Mark, Zier, Oliver
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2507.08787
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author McClymont, William
Tacchella, Sandro
Smith, Aaron
Kannan, Rahul
Garaldi, Enrico
Puchwein, Ewald
Isobe, Yuki
Ji, Xihan
Shen, Xuejian
Wang, Zihao
Belokurov, Vasily
Borrow, Josh
D'Eugenio, Francesco
Keating, Laura
Maiolino, Roberto
Monty, Stephanie
Vogelsberger, Mark
Zier, Oliver
author_facet McClymont, William
Tacchella, Sandro
Smith, Aaron
Kannan, Rahul
Garaldi, Enrico
Puchwein, Ewald
Isobe, Yuki
Ji, Xihan
Shen, Xuejian
Wang, Zihao
Belokurov, Vasily
Borrow, Josh
D'Eugenio, Francesco
Keating, Laura
Maiolino, Roberto
Monty, Stephanie
Vogelsberger, Mark
Zier, Oliver
contents We present an analysis of metallicities and chemical abundances at $3<z<12$ in the THESAN-ZOOM simulations. We find that smoothly curved gas-phase and stellar mass-metallicity relations (MZR) are already in place at $z\approx12$ and evolve slowly ($\sim$0.2 dex increase for gas, $\sim$0.4 dex increase for stars at a fixed stellar mass) down to $z=3$, governed largely by the efficiency with which galaxies retain their metals, rather than gas fraction. The canonical fundamental metallicity relation (FMR) survives in stars but breaks down and inverts for gas in low-mass galaxies ($M_\ast\lesssim10^{9}\mathrm{M_\odot}$) due to regular dilution by low-metallicity gas inflow. We find broad agreement of gas-phase N/O, Fe/O, and C/O with high-redshift observations, including the presence of nitrogen-rich galaxies (NRGs; $\log(\mathrm{N/O})>-0.6$) without the need for exotic yields in our chemical network. Instead, bursty star formation naturally generates order-of-magnitude excursions in N/O on $\lesssim$100 Myr timescales due to temporally differential galactic winds; after a starburst, stellar feedback expels gas, leaving a large population of asymptotic-giant-branch stars to dominate the enrichment of the relatively low-mass interstellar medium. NRGs lie below the main sequence and typically exhibit $\mathrm{EW}[H$β$]\lesssim40$ Å, in apparent tension with observed high-EW NRGs. This tension is reconciled if observed NRGs are in the initial stages of a subsequent starburst, illuminating previously enriched gas, which is supported by the finding of high SFR surface density nitrogen-rich giant molecular clouds.
format Preprint
id arxiv_https___arxiv_org_abs_2507_08787
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle The THESAN-ZOOM project: Mystery N/O more -- uncovering the origin of peculiar chemical abundances and a not-so-fundamental metallicity relation at $3<z<12$
McClymont, William
Tacchella, Sandro
Smith, Aaron
Kannan, Rahul
Garaldi, Enrico
Puchwein, Ewald
Isobe, Yuki
Ji, Xihan
Shen, Xuejian
Wang, Zihao
Belokurov, Vasily
Borrow, Josh
D'Eugenio, Francesco
Keating, Laura
Maiolino, Roberto
Monty, Stephanie
Vogelsberger, Mark
Zier, Oliver
Astrophysics of Galaxies
We present an analysis of metallicities and chemical abundances at $3<z<12$ in the THESAN-ZOOM simulations. We find that smoothly curved gas-phase and stellar mass-metallicity relations (MZR) are already in place at $z\approx12$ and evolve slowly ($\sim$0.2 dex increase for gas, $\sim$0.4 dex increase for stars at a fixed stellar mass) down to $z=3$, governed largely by the efficiency with which galaxies retain their metals, rather than gas fraction. The canonical fundamental metallicity relation (FMR) survives in stars but breaks down and inverts for gas in low-mass galaxies ($M_\ast\lesssim10^{9}\mathrm{M_\odot}$) due to regular dilution by low-metallicity gas inflow. We find broad agreement of gas-phase N/O, Fe/O, and C/O with high-redshift observations, including the presence of nitrogen-rich galaxies (NRGs; $\log(\mathrm{N/O})>-0.6$) without the need for exotic yields in our chemical network. Instead, bursty star formation naturally generates order-of-magnitude excursions in N/O on $\lesssim$100 Myr timescales due to temporally differential galactic winds; after a starburst, stellar feedback expels gas, leaving a large population of asymptotic-giant-branch stars to dominate the enrichment of the relatively low-mass interstellar medium. NRGs lie below the main sequence and typically exhibit $\mathrm{EW}[H$β$]\lesssim40$ Å, in apparent tension with observed high-EW NRGs. This tension is reconciled if observed NRGs are in the initial stages of a subsequent starburst, illuminating previously enriched gas, which is supported by the finding of high SFR surface density nitrogen-rich giant molecular clouds.
title The THESAN-ZOOM project: Mystery N/O more -- uncovering the origin of peculiar chemical abundances and a not-so-fundamental metallicity relation at $3<z<12$
topic Astrophysics of Galaxies
url https://arxiv.org/abs/2507.08787