Thermodynamic Geometric Constraint on the Spectrum of Markov Rate Matrices

Fuente: arXiv
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Main Authors: Xu, Guo-Hua, Kolchinsky, Artemy, Delvenne, Jean-Charles, Ito, Sosuke
Format: Preprint
Published: 2025
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author Xu, Guo-Hua
Kolchinsky, Artemy
Delvenne, Jean-Charles
Ito, Sosuke
author_facet Xu, Guo-Hua
Kolchinsky, Artemy
Delvenne, Jean-Charles
Ito, Sosuke
contents The spectrum of Markov generators encodes physical information beyond simple decay and oscillation, which reflects irreversibility and governs the structure of correlation functions. In this work, we prove an ellipse theorem that provides a universal thermodynamic geometric constraint on the spectrum of Markov rate matrices. The theorem states that all eigenvalues lie within a specific ellipse in the complex plane. In particular, the imaginary parts of the spectrum, which indicate oscillatory modes, are bounded by the maximum thermodynamic force associated with individual transitions. This spectral bound further constrains the initial short-time behavior of correlation functions between two arbitrary observables. Finally, we compare our result with a previously proposed conjecture, which remains an open problem and warrants further investigation.
format Preprint
id arxiv_https___arxiv_org_abs_2507_08938
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Thermodynamic Geometric Constraint on the Spectrum of Markov Rate Matrices
Xu, Guo-Hua
Kolchinsky, Artemy
Delvenne, Jean-Charles
Ito, Sosuke
Statistical Mechanics
The spectrum of Markov generators encodes physical information beyond simple decay and oscillation, which reflects irreversibility and governs the structure of correlation functions. In this work, we prove an ellipse theorem that provides a universal thermodynamic geometric constraint on the spectrum of Markov rate matrices. The theorem states that all eigenvalues lie within a specific ellipse in the complex plane. In particular, the imaginary parts of the spectrum, which indicate oscillatory modes, are bounded by the maximum thermodynamic force associated with individual transitions. This spectral bound further constrains the initial short-time behavior of correlation functions between two arbitrary observables. Finally, we compare our result with a previously proposed conjecture, which remains an open problem and warrants further investigation.
title Thermodynamic Geometric Constraint on the Spectrum of Markov Rate Matrices
topic Statistical Mechanics
url https://arxiv.org/abs/2507.08938