Electrostatically Assembled Open Square and Checkerboard Superlattices
Fuente:
arXiv
Gespeichert in:
| Hauptverfasser: | , , , , , , |
|---|---|
| Format: | Preprint |
| Veröffentlicht: |
2025
|
| Schlagworte: | |
| Online-Zugang: | |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| _version_ | 1866909972944650240 |
|---|---|
| author | Nayak, Binay P. Wang, Wenjie Zhang, Honghu Ocko, Benjamin M. Travesset, Alex Mallapragada, Surya K. Vaknin, David |
| author_facet | Nayak, Binay P. Wang, Wenjie Zhang, Honghu Ocko, Benjamin M. Travesset, Alex Mallapragada, Surya K. Vaknin, David |
| contents | Programmable assembly of nanoparticles into structures other than hexagonal lattices remains challenging. Assembling an open checkerboard or square lattice is harder to achieve compared to a close-packed hexagonal structure. Here, we introduce a unified, robust approach to assemble nanoparticles into a diverse family of two-dimensional superlattices at the liquid-air interface. Gold nanoparticles are grafted with pH-responsive, water-soluble poly(ethylene glycol) chains terminating in -COOH or -NH2 end groups, enabling control over interparticle interactions, while the grafted polymer's molecular weight dictates its conformation. This combined control crystallizes checkerboard, simple-square, and body-centered honeycomb superlattices. We find that even for identical nanoparticle core sizes, the polymer's molecular weight dictates superlattice symmetry and stability. Furthermore, tuning pH induces structural transitions between different lattice types. This method opens new avenues for the programmable fabrication of colloidal superstructures with tailored architectures. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2507_08989 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Electrostatically Assembled Open Square and Checkerboard Superlattices Nayak, Binay P. Wang, Wenjie Zhang, Honghu Ocko, Benjamin M. Travesset, Alex Mallapragada, Surya K. Vaknin, David Soft Condensed Matter Mesoscale and Nanoscale Physics Materials Science Programmable assembly of nanoparticles into structures other than hexagonal lattices remains challenging. Assembling an open checkerboard or square lattice is harder to achieve compared to a close-packed hexagonal structure. Here, we introduce a unified, robust approach to assemble nanoparticles into a diverse family of two-dimensional superlattices at the liquid-air interface. Gold nanoparticles are grafted with pH-responsive, water-soluble poly(ethylene glycol) chains terminating in -COOH or -NH2 end groups, enabling control over interparticle interactions, while the grafted polymer's molecular weight dictates its conformation. This combined control crystallizes checkerboard, simple-square, and body-centered honeycomb superlattices. We find that even for identical nanoparticle core sizes, the polymer's molecular weight dictates superlattice symmetry and stability. Furthermore, tuning pH induces structural transitions between different lattice types. This method opens new avenues for the programmable fabrication of colloidal superstructures with tailored architectures. |
| title | Electrostatically Assembled Open Square and Checkerboard Superlattices |
| topic | Soft Condensed Matter Mesoscale and Nanoscale Physics Materials Science |
| url | https://arxiv.org/abs/2507.08989 |