$WSe_2$ Monolayers Grown by Molecular Beam Epitaxy on hBN

Fuente: arXiv
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Autori principali: Kucharek, Julia, Raczyński, Mateusz, Bożek, Rafał, Kaleta, Anna, Kurowska, Bogusława, Bilska, Marta, Kret, Sławomir, Taniguchi, Takashi, Watanabe, Kenji, Kossacki, Piotr, Goryca, Mateusz, Pacuski, Wojciech
Natura: Preprint
Pubblicazione: 2025
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author Kucharek, Julia
Raczyński, Mateusz
Bożek, Rafał
Kaleta, Anna
Kurowska, Bogusława
Bilska, Marta
Kret, Sławomir
Taniguchi, Takashi
Watanabe, Kenji
Kossacki, Piotr
Goryca, Mateusz
Pacuski, Wojciech
author_facet Kucharek, Julia
Raczyński, Mateusz
Bożek, Rafał
Kaleta, Anna
Kurowska, Bogusława
Bilska, Marta
Kret, Sławomir
Taniguchi, Takashi
Watanabe, Kenji
Kossacki, Piotr
Goryca, Mateusz
Pacuski, Wojciech
contents A three-step process was developed for growing high-quality, optically uniform WSe2 monolayers by molecular beam epitaxy (MBE) with advantage of using hexagonal boron nitride (hBN). The process was optimized to maximize the efficiency of photoluminescence and promote formation of hexagonal WSe2 domains. Atomic force microscopy (AFM) was employed to estimate the dispersion of WSe2 hexagonal domains orientation. Monolayer character of the film was identified using optical methods and verified with high-resolution transmission electron microscopy (TEM) cross-section. Temperature-and-magnetic-field-dependent studies revealed the behaviour of exciton complexes to be analogical to that of exfoliated counterparts. Direct growth on hBN combined with uniform optical response proves this WSe2 superior to mechanically exfoliated WSe2 in terms of convenience of use and reproducibility. Provided results establish a significant progress in optical quality of epitaxially grown transition metal dichalcogenides (TMDs) monolayers and fabrication of large-scale functional devices.
format Preprint
id arxiv_https___arxiv_org_abs_2507_09275
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle $WSe_2$ Monolayers Grown by Molecular Beam Epitaxy on hBN
Kucharek, Julia
Raczyński, Mateusz
Bożek, Rafał
Kaleta, Anna
Kurowska, Bogusława
Bilska, Marta
Kret, Sławomir
Taniguchi, Takashi
Watanabe, Kenji
Kossacki, Piotr
Goryca, Mateusz
Pacuski, Wojciech
Materials Science
A three-step process was developed for growing high-quality, optically uniform WSe2 monolayers by molecular beam epitaxy (MBE) with advantage of using hexagonal boron nitride (hBN). The process was optimized to maximize the efficiency of photoluminescence and promote formation of hexagonal WSe2 domains. Atomic force microscopy (AFM) was employed to estimate the dispersion of WSe2 hexagonal domains orientation. Monolayer character of the film was identified using optical methods and verified with high-resolution transmission electron microscopy (TEM) cross-section. Temperature-and-magnetic-field-dependent studies revealed the behaviour of exciton complexes to be analogical to that of exfoliated counterparts. Direct growth on hBN combined with uniform optical response proves this WSe2 superior to mechanically exfoliated WSe2 in terms of convenience of use and reproducibility. Provided results establish a significant progress in optical quality of epitaxially grown transition metal dichalcogenides (TMDs) monolayers and fabrication of large-scale functional devices.
title $WSe_2$ Monolayers Grown by Molecular Beam Epitaxy on hBN
topic Materials Science
url https://arxiv.org/abs/2507.09275