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Main Authors: Volokhova, Alexandra, Ezzine, Léna Néhale, Gaiński, Piotr, Scimeca, Luca, Bengio, Emmanuel, Tossou, Prudencio, Bengio, Yoshua, Hernandez-Garcia, Alex
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2507.11759
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author Volokhova, Alexandra
Ezzine, Léna Néhale
Gaiński, Piotr
Scimeca, Luca
Bengio, Emmanuel
Tossou, Prudencio
Bengio, Yoshua
Hernandez-Garcia, Alex
author_facet Volokhova, Alexandra
Ezzine, Léna Néhale
Gaiński, Piotr
Scimeca, Luca
Bengio, Emmanuel
Tossou, Prudencio
Bengio, Yoshua
Hernandez-Garcia, Alex
contents Generating stable molecular conformations is crucial in several drug discovery applications, such as estimating the binding affinity of a molecule to a target. Recently, generative machine learning methods have emerged as a promising, more efficient method than molecular dynamics for sampling of conformations from the Boltzmann distribution. In this paper, we introduce Torsional-GFN, a conditional GFlowNet specifically designed to sample conformations of molecules proportionally to their Boltzmann distribution, using only a reward function as training signal. Conditioned on a molecular graph and its local structure (bond lengths and angles), Torsional-GFN samples rotations of its torsion angles. Our results demonstrate that Torsional-GFN is able to sample conformations approximately proportional to the Boltzmann distribution for multiple molecules with a single model, and allows for zero-shot generalization to unseen bond lengths and angles coming from the MD simulations for such molecules. Our work presents a promising avenue for scaling the proposed approach to larger molecular systems, achieving zero-shot generalization to unseen molecules, and including the generation of the local structure into the GFlowNet model.
format Preprint
id arxiv_https___arxiv_org_abs_2507_11759
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Torsional-GFN: a conditional conformation generator for small molecules
Volokhova, Alexandra
Ezzine, Léna Néhale
Gaiński, Piotr
Scimeca, Luca
Bengio, Emmanuel
Tossou, Prudencio
Bengio, Yoshua
Hernandez-Garcia, Alex
Machine Learning
Generating stable molecular conformations is crucial in several drug discovery applications, such as estimating the binding affinity of a molecule to a target. Recently, generative machine learning methods have emerged as a promising, more efficient method than molecular dynamics for sampling of conformations from the Boltzmann distribution. In this paper, we introduce Torsional-GFN, a conditional GFlowNet specifically designed to sample conformations of molecules proportionally to their Boltzmann distribution, using only a reward function as training signal. Conditioned on a molecular graph and its local structure (bond lengths and angles), Torsional-GFN samples rotations of its torsion angles. Our results demonstrate that Torsional-GFN is able to sample conformations approximately proportional to the Boltzmann distribution for multiple molecules with a single model, and allows for zero-shot generalization to unseen bond lengths and angles coming from the MD simulations for such molecules. Our work presents a promising avenue for scaling the proposed approach to larger molecular systems, achieving zero-shot generalization to unseen molecules, and including the generation of the local structure into the GFlowNet model.
title Torsional-GFN: a conditional conformation generator for small molecules
topic Machine Learning
url https://arxiv.org/abs/2507.11759