Suppression of charge-density wave and superconductivity in a lithiated NbSe$_2$ monolayer

Fuente: arXiv
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Autori principali: Paudyal, Hari, Flatté, Michael E.
Natura: Preprint
Pubblicazione: 2025
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author Paudyal, Hari
Flatté, Michael E.
author_facet Paudyal, Hari
Flatté, Michael E.
contents We present an \textit{ab initio} investigation of the long-range charge density wave (CDW) order and superconducting properties of the pristine and lithiated NbSe$_2$ monolayer. Stable CDW structures are obtained through atomic reconstruction driven by soft-mode distortions and lithiation, respectively, lead to significant electronic modifications that suppress the CDW order. This suppression is attributed to anisotropic atomic distortions, along with a reduction in the electronic density of states at the Fermi level. As a result, the electron--phonon coupling strength is suppressed, particularly in the lithiated structure, due to reduced contributions from low-frequency phonons, primarily associated with in-plane Nb vibrations. Finally, we observe a sizable anisotropy in the superconducting gap on the Fermi surface, with a superconducting transition temperature of approximately 8~K in the distorted, and 4~K in the lithiated, CDW NbSe$_2$ monolayer.
format Preprint
id arxiv_https___arxiv_org_abs_2507_11856
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Suppression of charge-density wave and superconductivity in a lithiated NbSe$_2$ monolayer
Paudyal, Hari
Flatté, Michael E.
Superconductivity
We present an \textit{ab initio} investigation of the long-range charge density wave (CDW) order and superconducting properties of the pristine and lithiated NbSe$_2$ monolayer. Stable CDW structures are obtained through atomic reconstruction driven by soft-mode distortions and lithiation, respectively, lead to significant electronic modifications that suppress the CDW order. This suppression is attributed to anisotropic atomic distortions, along with a reduction in the electronic density of states at the Fermi level. As a result, the electron--phonon coupling strength is suppressed, particularly in the lithiated structure, due to reduced contributions from low-frequency phonons, primarily associated with in-plane Nb vibrations. Finally, we observe a sizable anisotropy in the superconducting gap on the Fermi surface, with a superconducting transition temperature of approximately 8~K in the distorted, and 4~K in the lithiated, CDW NbSe$_2$ monolayer.
title Suppression of charge-density wave and superconductivity in a lithiated NbSe$_2$ monolayer
topic Superconductivity
url https://arxiv.org/abs/2507.11856