Variational studies of ro-vibrational spectra of DT$^+$ and T$_2^+$ ions

Fuente: arXiv
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Main Authors: Aznabayev, D. T., Zhomartova, D. B., Bekbaev, A. K., Korobov, Vladimir I.
Format: Preprint
Published: 2025
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author Aznabayev, D. T.
Zhomartova, D. B.
Bekbaev, A. K.
Korobov, Vladimir I.
author_facet Aznabayev, D. T.
Zhomartova, D. B.
Bekbaev, A. K.
Korobov, Vladimir I.
contents In this work we study the last two hydrogen molecular ion isotopologues: DT$^+$ and T$_2^+$, for which high-precision calculations have not yet been made. We obtain the nonrelativistic solutions of the Schrödinger equation for the wide range of vibrational states up to the highest possible vibrational $1sσ_g$ state which are of spectroscopic precision. Transition amplitudes for electric dipole transitions, leading-order relativistic corrections and coefficients of the effective hyperfine structure Hamiltonians for both DT$^+$ and T$_2^+$ are also calculated.
format Preprint
id arxiv_https___arxiv_org_abs_2507_12243
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Variational studies of ro-vibrational spectra of DT$^+$ and T$_2^+$ ions
Aznabayev, D. T.
Zhomartova, D. B.
Bekbaev, A. K.
Korobov, Vladimir I.
Atomic Physics
In this work we study the last two hydrogen molecular ion isotopologues: DT$^+$ and T$_2^+$, for which high-precision calculations have not yet been made. We obtain the nonrelativistic solutions of the Schrödinger equation for the wide range of vibrational states up to the highest possible vibrational $1sσ_g$ state which are of spectroscopic precision. Transition amplitudes for electric dipole transitions, leading-order relativistic corrections and coefficients of the effective hyperfine structure Hamiltonians for both DT$^+$ and T$_2^+$ are also calculated.
title Variational studies of ro-vibrational spectra of DT$^+$ and T$_2^+$ ions
topic Atomic Physics
url https://arxiv.org/abs/2507.12243