Alignment behavior of 2D diopsides (d-silicates) under the influence of an AC electric field
Fuente:
arXiv
Enregistré dans:
| Auteurs principaux: | , , , , , , , , , , |
|---|---|
| Format: | Preprint |
| Publié: |
2025
|
| Sujets: | |
| Accès en ligne: | |
| Tags: |
Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!
|
| _version_ | 1866910014973673472 |
|---|---|
| author | Mishra, Himakshi Slathia, Surbhi Ipaves, Bruno de Oliveira, Raphael Benjamim Junior, Marcelo Lopes Pereira Tromer, Raphael Matozo Costin, Gelu Glavin, Nicholas R. Roy, Ajit K. Galvao, Douglas Soares Tiwary, Chandra Shekar |
| author_facet | Mishra, Himakshi Slathia, Surbhi Ipaves, Bruno de Oliveira, Raphael Benjamim Junior, Marcelo Lopes Pereira Tromer, Raphael Matozo Costin, Gelu Glavin, Nicholas R. Roy, Ajit K. Galvao, Douglas Soares Tiwary, Chandra Shekar |
| contents | Controlling the alignment of two dimensional (2D) materials is crucial for optimizing their electronic and mechanical properties in next generation devices. This study explores how electric fields can manipulate the orientation of 2D diopside (CaMgSi2O6) flakes, a flexible silicate material, through a phenomenon called flexoelectricity, where applied voltage generates mechanical strain. We exfoliated diopside crystals into ultrathin flakes, placed them on microelectrodes, and used AC electric fields to induce alignment via acoustic strain. Raman spectroscopy showed that the flakes reoriented/realigned under the field, with vibrational peaks weakening most at high frequencies (10 MHz). Electrical tests revealed this alignment improves conductivity by 20-30%, as straightened flakes create better pathways for current flow. Fully atomistic molecular dynamics simulations further explained how these flakes naturally align on surfaces within picoseconds, matching our experimental observations. Together, these findings demonstrate a practical way to tune diopside properties using electric fields, opening doors for its use in flexible electronics, sensors, and energy devices. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2507_13962 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Alignment behavior of 2D diopsides (d-silicates) under the influence of an AC electric field Mishra, Himakshi Slathia, Surbhi Ipaves, Bruno de Oliveira, Raphael Benjamim Junior, Marcelo Lopes Pereira Tromer, Raphael Matozo Costin, Gelu Glavin, Nicholas R. Roy, Ajit K. Galvao, Douglas Soares Tiwary, Chandra Shekar Mesoscale and Nanoscale Physics Materials Science Controlling the alignment of two dimensional (2D) materials is crucial for optimizing their electronic and mechanical properties in next generation devices. This study explores how electric fields can manipulate the orientation of 2D diopside (CaMgSi2O6) flakes, a flexible silicate material, through a phenomenon called flexoelectricity, where applied voltage generates mechanical strain. We exfoliated diopside crystals into ultrathin flakes, placed them on microelectrodes, and used AC electric fields to induce alignment via acoustic strain. Raman spectroscopy showed that the flakes reoriented/realigned under the field, with vibrational peaks weakening most at high frequencies (10 MHz). Electrical tests revealed this alignment improves conductivity by 20-30%, as straightened flakes create better pathways for current flow. Fully atomistic molecular dynamics simulations further explained how these flakes naturally align on surfaces within picoseconds, matching our experimental observations. Together, these findings demonstrate a practical way to tune diopside properties using electric fields, opening doors for its use in flexible electronics, sensors, and energy devices. |
| title | Alignment behavior of 2D diopsides (d-silicates) under the influence of an AC electric field |
| topic | Mesoscale and Nanoscale Physics Materials Science |
| url | https://arxiv.org/abs/2507.13962 |