Coupling of magnetic and lattice collective excitations in the 2D van der Waals antiferromagnet FePS$_{3}$

Fuente: arXiv
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Autori principali: Panda, Kartik, Kapon, Itzik, Dumcenco, Dumitru, van der Marel, Dirk, Kuzmenko, Alexey, Bachar, Nimrod
Natura: Preprint
Pubblicazione: 2025
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author Panda, Kartik
Kapon, Itzik
Dumcenco, Dumitru
van der Marel, Dirk
Kuzmenko, Alexey
Bachar, Nimrod
author_facet Panda, Kartik
Kapon, Itzik
Dumcenco, Dumitru
van der Marel, Dirk
Kuzmenko, Alexey
Bachar, Nimrod
contents We combine polarized infrared magneto-transmission and Faraday angle rotation measurements to map the collective excitations of the van der Waals antiferromagnet FePS$_3$. Below the Néel temperature ($T_\mathrm{N} \approx 118$ K), the phonon spectrum becomes strongly anisotropic, while a prominent excitation at 122 cm$^{-1}$ (15 meV) hardens on cooling and splits linearly with magnetic field,identifying its magnetic origin. From absolute transmission and Faraday angle measurements, we reconstruct the circular optical conductivities, revealing a pronounced dichroism of the field-split excitations. The upper branch near 129 cm$^{-1}$ shows an anomalously reduced dichroism, consistent with spin-phonon hybridization with a nearby infrared phonon. Several phonons exhibit sizable Faraday rotation, and Raman-active modes appear in the infrared spectra. Together with a broad mid-infrared band near 900 cm$^{-1}$ emerging only below $T_\mathrm{N}$, these observations point to inversion-symmetry breaking in the magnetic state. A weak Faraday feature near 320 cm$^{-1}$ ($\sim 40$ meV) further supports the presence of a higher-energy magnetic excitation. These findings underscore the intricate interplay between magnetic and lattice degrees of freedom in FePS$_3$ and establish its relevance for exploring spin-lattice interactions in two-dimensional antiferromagnetic materials.
format Preprint
id arxiv_https___arxiv_org_abs_2507_17238
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Coupling of magnetic and lattice collective excitations in the 2D van der Waals antiferromagnet FePS$_{3}$
Panda, Kartik
Kapon, Itzik
Dumcenco, Dumitru
van der Marel, Dirk
Kuzmenko, Alexey
Bachar, Nimrod
Strongly Correlated Electrons
We combine polarized infrared magneto-transmission and Faraday angle rotation measurements to map the collective excitations of the van der Waals antiferromagnet FePS$_3$. Below the Néel temperature ($T_\mathrm{N} \approx 118$ K), the phonon spectrum becomes strongly anisotropic, while a prominent excitation at 122 cm$^{-1}$ (15 meV) hardens on cooling and splits linearly with magnetic field,identifying its magnetic origin. From absolute transmission and Faraday angle measurements, we reconstruct the circular optical conductivities, revealing a pronounced dichroism of the field-split excitations. The upper branch near 129 cm$^{-1}$ shows an anomalously reduced dichroism, consistent with spin-phonon hybridization with a nearby infrared phonon. Several phonons exhibit sizable Faraday rotation, and Raman-active modes appear in the infrared spectra. Together with a broad mid-infrared band near 900 cm$^{-1}$ emerging only below $T_\mathrm{N}$, these observations point to inversion-symmetry breaking in the magnetic state. A weak Faraday feature near 320 cm$^{-1}$ ($\sim 40$ meV) further supports the presence of a higher-energy magnetic excitation. These findings underscore the intricate interplay between magnetic and lattice degrees of freedom in FePS$_3$ and establish its relevance for exploring spin-lattice interactions in two-dimensional antiferromagnetic materials.
title Coupling of magnetic and lattice collective excitations in the 2D van der Waals antiferromagnet FePS$_{3}$
topic Strongly Correlated Electrons
url https://arxiv.org/abs/2507.17238