Printable Nanocomposites with Superparamagnetic Maghemite ($γ$-Fe$_2$O$_3$) Particles for Microinductor-core Applications

Fuente: arXiv
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Main Authors: Zambach, Mathias, Varón, Miriam, Veile, Thomas, Sanusi, Bima N., Knaapila, Matti, Jørgensen, Anders M., Almásy, László, Johansson, Christer, Ouyang, Ziwei, Beleggia, M., Frandsen, Cathrine
Format: Preprint
Published: 2025
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author Zambach, Mathias
Varón, Miriam
Veile, Thomas
Sanusi, Bima N.
Knaapila, Matti
Jørgensen, Anders M.
Almásy, László
Johansson, Christer
Ouyang, Ziwei
Beleggia, M.
Frandsen, Cathrine
author_facet Zambach, Mathias
Varón, Miriam
Veile, Thomas
Sanusi, Bima N.
Knaapila, Matti
Jørgensen, Anders M.
Almásy, László
Johansson, Christer
Ouyang, Ziwei
Beleggia, M.
Frandsen, Cathrine
contents We here present printable and castable magnetic nanocomposites containing superparamagnetic 11$\pm$3 nm $γ$-Fe$_2$O$_3$ particles in an insulating poly-vinyl alcohol polymer matrix. The nanocomposites feature well-dispersed particles with volume fractions between 10 and 45 \%, as confirmed by small-angle neutron scattering. The magnetic volume susceptibility is as high as 17, together with negligible hysteresis at low frequency, and constant AC-response up to the high-kHz range. Measured hysteresis curves at 100-900 kHz with up to 110 mT induced $B$-fields in the nanocomposite show that power losses depend on $B$-field squared, and frequency to the power of 1-1.3. The only loss mechanism in the nanocomposite is hysteresis losses at $>$100 kHz frequencies, where the largest particles in the 11$\pm$3 nm distribution transition from the superparamagnetic to blocked regime. To mitigate the resulting hysteresis losses (up 10$^2$-10$^5$ kW/m$^3$) a more narrow particle size distribution could be used for future materials. The presented material is eddy current-free and easily integrated into micro-fabrication protocols, as we demonstrate by fabrication of 3-turn print circuit board based inductors with cast/manual printed nanocomposite inductor cores, on which induction has been measured up to 100 MHz.
format Preprint
id arxiv_https___arxiv_org_abs_2507_23522
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Printable Nanocomposites with Superparamagnetic Maghemite ($γ$-Fe$_2$O$_3$) Particles for Microinductor-core Applications
Zambach, Mathias
Varón, Miriam
Veile, Thomas
Sanusi, Bima N.
Knaapila, Matti
Jørgensen, Anders M.
Almásy, László
Johansson, Christer
Ouyang, Ziwei
Beleggia, M.
Frandsen, Cathrine
Mesoscale and Nanoscale Physics
Applied Physics
We here present printable and castable magnetic nanocomposites containing superparamagnetic 11$\pm$3 nm $γ$-Fe$_2$O$_3$ particles in an insulating poly-vinyl alcohol polymer matrix. The nanocomposites feature well-dispersed particles with volume fractions between 10 and 45 \%, as confirmed by small-angle neutron scattering. The magnetic volume susceptibility is as high as 17, together with negligible hysteresis at low frequency, and constant AC-response up to the high-kHz range. Measured hysteresis curves at 100-900 kHz with up to 110 mT induced $B$-fields in the nanocomposite show that power losses depend on $B$-field squared, and frequency to the power of 1-1.3. The only loss mechanism in the nanocomposite is hysteresis losses at $>$100 kHz frequencies, where the largest particles in the 11$\pm$3 nm distribution transition from the superparamagnetic to blocked regime. To mitigate the resulting hysteresis losses (up 10$^2$-10$^5$ kW/m$^3$) a more narrow particle size distribution could be used for future materials. The presented material is eddy current-free and easily integrated into micro-fabrication protocols, as we demonstrate by fabrication of 3-turn print circuit board based inductors with cast/manual printed nanocomposite inductor cores, on which induction has been measured up to 100 MHz.
title Printable Nanocomposites with Superparamagnetic Maghemite ($γ$-Fe$_2$O$_3$) Particles for Microinductor-core Applications
topic Mesoscale and Nanoscale Physics
Applied Physics
url https://arxiv.org/abs/2507.23522