The Open DAC 2025 Dataset for Sorbent Discovery in Direct Air Capture

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Main Authors: Sriram, Anuroop, Brabson, Logan M., Yu, Xiaohan, Choi, Sihoon, Abdelmaqsoud, Kareem, Moubarak, Elias, de Haan, Pim, Löwe, Sindy, Brehmer, Johann, Kitchin, John R., Welling, Max, Zitnick, C. Lawrence, Ulissi, Zachary, Medford, Andrew J., Sholl, David S.
Format: Preprint
Published: 2025
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author Sriram, Anuroop
Brabson, Logan M.
Yu, Xiaohan
Choi, Sihoon
Abdelmaqsoud, Kareem
Moubarak, Elias
de Haan, Pim
Löwe, Sindy
Brehmer, Johann
Kitchin, John R.
Welling, Max
Zitnick, C. Lawrence
Ulissi, Zachary
Medford, Andrew J.
Sholl, David S.
author_facet Sriram, Anuroop
Brabson, Logan M.
Yu, Xiaohan
Choi, Sihoon
Abdelmaqsoud, Kareem
Moubarak, Elias
de Haan, Pim
Löwe, Sindy
Brehmer, Johann
Kitchin, John R.
Welling, Max
Zitnick, C. Lawrence
Ulissi, Zachary
Medford, Andrew J.
Sholl, David S.
contents Identifying useful sorbent materials for direct air capture (DAC) from humid air remains a challenge. We present the Open DAC 2025 (ODAC25) dataset, a significant expansion and improvement upon ODAC23 (Sriram et al., ACS Central Science, 10 (2024) 923), comprising nearly 60 million DFT single-point calculations for CO$_2$, H$_2$O, N$_2$, and O$_2$ adsorption in 15,000 MOFs. ODAC25 introduces chemical and configurational diversity through functionalized MOFs, high-energy GCMC-derived placements, and synthetically generated frameworks. ODAC25 also significantly improves upon the accuracy of DFT calculations and the treatment of flexible MOFs in ODAC23. Along with the dataset, we release new state-of-the-art machine-learned interatomic potentials trained on ODAC25 and evaluate them on adsorption energy and Henry's law coefficient predictions.
format Preprint
id arxiv_https___arxiv_org_abs_2508_03162
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle The Open DAC 2025 Dataset for Sorbent Discovery in Direct Air Capture
Sriram, Anuroop
Brabson, Logan M.
Yu, Xiaohan
Choi, Sihoon
Abdelmaqsoud, Kareem
Moubarak, Elias
de Haan, Pim
Löwe, Sindy
Brehmer, Johann
Kitchin, John R.
Welling, Max
Zitnick, C. Lawrence
Ulissi, Zachary
Medford, Andrew J.
Sholl, David S.
Materials Science
Machine Learning
Chemical Physics
Identifying useful sorbent materials for direct air capture (DAC) from humid air remains a challenge. We present the Open DAC 2025 (ODAC25) dataset, a significant expansion and improvement upon ODAC23 (Sriram et al., ACS Central Science, 10 (2024) 923), comprising nearly 60 million DFT single-point calculations for CO$_2$, H$_2$O, N$_2$, and O$_2$ adsorption in 15,000 MOFs. ODAC25 introduces chemical and configurational diversity through functionalized MOFs, high-energy GCMC-derived placements, and synthetically generated frameworks. ODAC25 also significantly improves upon the accuracy of DFT calculations and the treatment of flexible MOFs in ODAC23. Along with the dataset, we release new state-of-the-art machine-learned interatomic potentials trained on ODAC25 and evaluate them on adsorption energy and Henry's law coefficient predictions.
title The Open DAC 2025 Dataset for Sorbent Discovery in Direct Air Capture
topic Materials Science
Machine Learning
Chemical Physics
url https://arxiv.org/abs/2508.03162