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Main Authors: Burger, Nikolaos A., Petrunin, Alexander V., Schweins, Ann E. Terry Ralf, Scotti, Andrea
Format: Preprint
Published: 2025
Subjects:
Online Access:https://arxiv.org/abs/2508.04244
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author Burger, Nikolaos A.
Petrunin, Alexander V.
Schweins, Ann E. Terry Ralf
Scotti, Andrea
author_facet Burger, Nikolaos A.
Petrunin, Alexander V.
Schweins, Ann E. Terry Ralf
Scotti, Andrea
contents Concentrated suspensions of small ultra-soft colloids (ultra-low crosslinked microgels) are investigated with scattering and steady shear rheology to capture their equilibrium dynamics. The suspensions lack dynamic arrest, although the slow relaxation time $τ_2$ follows exponential growth with increasing generalized packing fraction, $ζ$. The zero-shear viscosity grows weakly with $ζ$, and never diverges in contrast to other soft glass formers, e.g.~star-polymers, microgels, green particles. Their high compressibility allows these ultra-soft spheres to diffuse even in overcrowded environments.
format Preprint
id arxiv_https___arxiv_org_abs_2508_04244
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Suspensions of small ultra-soft colloids remain liquids in overcrowded conditions
Burger, Nikolaos A.
Petrunin, Alexander V.
Schweins, Ann E. Terry Ralf
Scotti, Andrea
Soft Condensed Matter
Chemical Physics
Concentrated suspensions of small ultra-soft colloids (ultra-low crosslinked microgels) are investigated with scattering and steady shear rheology to capture their equilibrium dynamics. The suspensions lack dynamic arrest, although the slow relaxation time $τ_2$ follows exponential growth with increasing generalized packing fraction, $ζ$. The zero-shear viscosity grows weakly with $ζ$, and never diverges in contrast to other soft glass formers, e.g.~star-polymers, microgels, green particles. Their high compressibility allows these ultra-soft spheres to diffuse even in overcrowded environments.
title Suspensions of small ultra-soft colloids remain liquids in overcrowded conditions
topic Soft Condensed Matter
Chemical Physics
url https://arxiv.org/abs/2508.04244