Strongly correlated electronic superconductivity in the noncentrosymmetric Re-Os-based high/medium-entropy alloys

Fuente: arXiv
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Autores principales: Chen, Rui, Li, Longfu, Zeng, Lingyong, Li, Kuan, Yu, Peifeng, Wang, Kangwang, Xiang, Zaichen, Wang, Shuangyue, Qin, Jingjun, Zhang, Wanyi, Li, Yucheng, Shang, Tian, Luo, Huixia
Formato: Preprint
Publicado: 2025
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author Chen, Rui
Li, Longfu
Zeng, Lingyong
Li, Kuan
Yu, Peifeng
Wang, Kangwang
Xiang, Zaichen
Wang, Shuangyue
Qin, Jingjun
Zhang, Wanyi
Li, Yucheng
Shang, Tian
Luo, Huixia
author_facet Chen, Rui
Li, Longfu
Zeng, Lingyong
Li, Kuan
Yu, Peifeng
Wang, Kangwang
Xiang, Zaichen
Wang, Shuangyue
Qin, Jingjun
Zhang, Wanyi
Li, Yucheng
Shang, Tian
Luo, Huixia
contents The class of unconventional superconductors, particularly noncentrosymmetric superconductors, has been highly considered as potential materials for understanding the complex properties of quantum materials. Here, five previously unreported Re3.5Os3.5Ta0.5Hf0.5Nb3, Re3Os3Ta0.5Hf0.5Nb3, Re3.5Os3.5Mo0.5Hf0.5Nb3, Re3.5Os3.5Mo0.5W0.5Nb3, and Re3Os3Mo0.5Hf0.5Nb3 Re-Os-based high/medium-entropy alloys (MEAs-HEAs) with valence electron count ranging from 6.45 to 6.81 were synthesized and investigated using x-ray diffraction, transport, magnetization, and specific heat measurements. Our analyses confirm that all five compounds crystallize in a noncentrosymmetric α-Mn-type structure and exhibit type-II superconductivity with Tc values from 4.20 K to 5.11 K, respectively. Unexpectedly, despite being immersed in an acidic environment for one month, the structures and superconducting properties of HEAs remain stable. Our findings indicate that the Tc increases with an increasing valence electron count in MEAs-HEAs. Furthermore, these noncentrosymmetric α-Mn-type HEA superconductors have large Kadowaki-Woods ratios (KWR), implying the presence of strong electronic correlations.
format Preprint
id arxiv_https___arxiv_org_abs_2508_05010
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Strongly correlated electronic superconductivity in the noncentrosymmetric Re-Os-based high/medium-entropy alloys
Chen, Rui
Li, Longfu
Zeng, Lingyong
Li, Kuan
Yu, Peifeng
Wang, Kangwang
Xiang, Zaichen
Wang, Shuangyue
Qin, Jingjun
Zhang, Wanyi
Li, Yucheng
Shang, Tian
Luo, Huixia
Superconductivity
The class of unconventional superconductors, particularly noncentrosymmetric superconductors, has been highly considered as potential materials for understanding the complex properties of quantum materials. Here, five previously unreported Re3.5Os3.5Ta0.5Hf0.5Nb3, Re3Os3Ta0.5Hf0.5Nb3, Re3.5Os3.5Mo0.5Hf0.5Nb3, Re3.5Os3.5Mo0.5W0.5Nb3, and Re3Os3Mo0.5Hf0.5Nb3 Re-Os-based high/medium-entropy alloys (MEAs-HEAs) with valence electron count ranging from 6.45 to 6.81 were synthesized and investigated using x-ray diffraction, transport, magnetization, and specific heat measurements. Our analyses confirm that all five compounds crystallize in a noncentrosymmetric α-Mn-type structure and exhibit type-II superconductivity with Tc values from 4.20 K to 5.11 K, respectively. Unexpectedly, despite being immersed in an acidic environment for one month, the structures and superconducting properties of HEAs remain stable. Our findings indicate that the Tc increases with an increasing valence electron count in MEAs-HEAs. Furthermore, these noncentrosymmetric α-Mn-type HEA superconductors have large Kadowaki-Woods ratios (KWR), implying the presence of strong electronic correlations.
title Strongly correlated electronic superconductivity in the noncentrosymmetric Re-Os-based high/medium-entropy alloys
topic Superconductivity
url https://arxiv.org/abs/2508.05010