Quantifying thermal water dissociation in the dayside photosphere of WASP-121 b using NIRPS

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Main Authors: Bazinet, Luc, Allart, Romain, Benneke, Björn, Pelletier, Stefan, Wardenier, Joost P., Cook, Neil J., Forveille, Thierry, Nielsen, Louise D., Moulla, Khaled Al, Artigau, Étienne, Baron, Frédérique, Barros, Susana C. C., Bonfils, Xavier, Bouchy, François, Bryan, Marta, Martins, Bruno L. Canto, Cloutier, Ryan, Cowan, Nicolas B., de Freitas, Daniel Brito, De Medeiros, Jose Renan, Delfosse, Xavier, Doyon, René, Dumusque, Xavier, Ehrenreich, David, Hernández, Jonay I. González, Lafrenière, David, Leão, Izan de Castro, Lovis, Christophe, Malo, Lison, Melo, Claudio, Mignon, Lucile, Mordasini, Christoph, Pepe, Francesco, Rebolo, Rafael, Rowe, Jason, Santos, Nuno C., Ségransan, Damien, Mascareño, Alejandro Suárez, Udry, Stéphane, Valencia, Diana, Wade, Gregg, Abreu, Manuel, Aguiar, José L. A., Allain, Guillaume, Arial, Tomy, Auger, Hugues, Blind, Nicolas, Bohlender, David, Boucher, Anne, Bourrier, Vincent, Bovay, Sébastien, Broeg, Christopher, Brousseau, Denis, Cabral, Alexandre, Cadieux, Charles, Carmona, Andres, Challita, Zalpha, Chazelas, Bruno, Coelho, João, Cointepas, Marion, Silva, Ana Rita Costa, Coulombe, Louis-Philippe, Cristo, Eduardo, Darveau-Bernier, Antoine, Dauplaise, Laurie, Gomes, Roseane de Lima, Fontinele, Dasaev O., Frensch, Yolanda G. C., Genest, Frédéric, Genolet, Ludovic, Témich, Félix Gracia, Hernandez, Olivier, Hoeijmakers, H. Jens, Hubin, Norbert, Jayawardhana, Ray, Käufl, Hans-Ulrich, Kerley, Dan, Kolb, Johann, Krishnamurthy, Vigneshwaran, Kung, Benjamin, Lamontagne, Pierrot, Lim, Olivia, Curto, Gaspare Lo, Rasilla, José Luis, Martins, Allan M., Matthews, Jaymie, Mayer, Jean-Sébastien, Messias, Yuri S., Metchev, Stan, Mounzer, Dany, Nari, Nicola, Osborn, Ares, Ouellet, Mathieu, Parc, Léna, Pasquini, Luca, Peroux, Céline, Piaulet-Ghorayeb, Caroline, Pompei, Emanuela, Poulin-Girard, Anne-Sophie, Reshetov, Vladimir, Saint-Antoine, Jonathan, Sarajlic, Mirsad, Schnell, Robin, Segovia, Alex, Seidel, Julia, Silber, Armin, Sinclair, Peter, Sordet, Michael, Sosnowska, Danuta, Srivastava, Avidaan, Stefanov, Atanas K., Teixeira, Márcio A., Thibault, Simon, Vallée, Philippe, Vandal, Thomas, Vaulato, Valentina, Wehbe, Bachar, Weisserman, Drew, Wevers, Ivan, Wildi, François, Yariv, Vincent, Zins, Gérard
Format: Preprint
Published: 2025
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author Bazinet, Luc
Allart, Romain
Benneke, Björn
Pelletier, Stefan
Wardenier, Joost P.
Cook, Neil J.
Forveille, Thierry
Nielsen, Louise D.
Moulla, Khaled Al
Artigau, Étienne
Baron, Frédérique
Barros, Susana C. C.
Bonfils, Xavier
Bouchy, François
Bryan, Marta
Martins, Bruno L. Canto
Cloutier, Ryan
Cowan, Nicolas B.
de Freitas, Daniel Brito
De Medeiros, Jose Renan
Delfosse, Xavier
Doyon, René
Dumusque, Xavier
Ehrenreich, David
Hernández, Jonay I. González
Lafrenière, David
Leão, Izan de Castro
Lovis, Christophe
Malo, Lison
Melo, Claudio
Mignon, Lucile
Mordasini, Christoph
Pepe, Francesco
Rebolo, Rafael
Rowe, Jason
Santos, Nuno C.
Ségransan, Damien
Mascareño, Alejandro Suárez
Udry, Stéphane
Valencia, Diana
Wade, Gregg
Abreu, Manuel
Aguiar, José L. A.
Allain, Guillaume
Arial, Tomy
Auger, Hugues
Blind, Nicolas
Bohlender, David
Boucher, Anne
Bourrier, Vincent
Bovay, Sébastien
Broeg, Christopher
Brousseau, Denis
Cabral, Alexandre
Cadieux, Charles
Carmona, Andres
Challita, Zalpha
Chazelas, Bruno
Coelho, João
Cointepas, Marion
Silva, Ana Rita Costa
Coulombe, Louis-Philippe
Cristo, Eduardo
Darveau-Bernier, Antoine
Dauplaise, Laurie
Gomes, Roseane de Lima
Fontinele, Dasaev O.
Frensch, Yolanda G. C.
Genest, Frédéric
Genolet, Ludovic
Témich, Félix Gracia
Hernandez, Olivier
Hoeijmakers, H. Jens
Hubin, Norbert
Jayawardhana, Ray
Käufl, Hans-Ulrich
Kerley, Dan
Kolb, Johann
Krishnamurthy, Vigneshwaran
Kung, Benjamin
Lamontagne, Pierrot
Lim, Olivia
Curto, Gaspare Lo
Rasilla, José Luis
Martins, Allan M.
Matthews, Jaymie
Mayer, Jean-Sébastien
Messias, Yuri S.
Metchev, Stan
Mounzer, Dany
Nari, Nicola
Osborn, Ares
Ouellet, Mathieu
Parc, Léna
Pasquini, Luca
Peroux, Céline
Piaulet-Ghorayeb, Caroline
Pompei, Emanuela
Poulin-Girard, Anne-Sophie
Reshetov, Vladimir
Saint-Antoine, Jonathan
Sarajlic, Mirsad
Schnell, Robin
Segovia, Alex
Seidel, Julia
Silber, Armin
Sinclair, Peter
Sordet, Michael
Sosnowska, Danuta
Srivastava, Avidaan
Stefanov, Atanas K.
Teixeira, Márcio A.
Thibault, Simon
Vallée, Philippe
Vandal, Thomas
Vaulato, Valentina
Wehbe, Bachar
Weisserman, Drew
Wevers, Ivan
Wildi, François
Yariv, Vincent
Zins, Gérard
author_facet Bazinet, Luc
Allart, Romain
Benneke, Björn
Pelletier, Stefan
Wardenier, Joost P.
Cook, Neil J.
Forveille, Thierry
Nielsen, Louise D.
Moulla, Khaled Al
Artigau, Étienne
Baron, Frédérique
Barros, Susana C. C.
Bonfils, Xavier
Bouchy, François
Bryan, Marta
Martins, Bruno L. Canto
Cloutier, Ryan
Cowan, Nicolas B.
de Freitas, Daniel Brito
De Medeiros, Jose Renan
Delfosse, Xavier
Doyon, René
Dumusque, Xavier
Ehrenreich, David
Hernández, Jonay I. González
Lafrenière, David
Leão, Izan de Castro
Lovis, Christophe
Malo, Lison
Melo, Claudio
Mignon, Lucile
Mordasini, Christoph
Pepe, Francesco
Rebolo, Rafael
Rowe, Jason
Santos, Nuno C.
Ségransan, Damien
Mascareño, Alejandro Suárez
Udry, Stéphane
Valencia, Diana
Wade, Gregg
Abreu, Manuel
Aguiar, José L. A.
Allain, Guillaume
Arial, Tomy
Auger, Hugues
Blind, Nicolas
Bohlender, David
Boucher, Anne
Bourrier, Vincent
Bovay, Sébastien
Broeg, Christopher
Brousseau, Denis
Cabral, Alexandre
Cadieux, Charles
Carmona, Andres
Challita, Zalpha
Chazelas, Bruno
Coelho, João
Cointepas, Marion
Silva, Ana Rita Costa
Coulombe, Louis-Philippe
Cristo, Eduardo
Darveau-Bernier, Antoine
Dauplaise, Laurie
Gomes, Roseane de Lima
Fontinele, Dasaev O.
Frensch, Yolanda G. C.
Genest, Frédéric
Genolet, Ludovic
Témich, Félix Gracia
Hernandez, Olivier
Hoeijmakers, H. Jens
Hubin, Norbert
Jayawardhana, Ray
Käufl, Hans-Ulrich
Kerley, Dan
Kolb, Johann
Krishnamurthy, Vigneshwaran
Kung, Benjamin
Lamontagne, Pierrot
Lim, Olivia
Curto, Gaspare Lo
Rasilla, José Luis
Martins, Allan M.
Matthews, Jaymie
Mayer, Jean-Sébastien
Messias, Yuri S.
Metchev, Stan
Mounzer, Dany
Nari, Nicola
Osborn, Ares
Ouellet, Mathieu
Parc, Léna
Pasquini, Luca
Peroux, Céline
Piaulet-Ghorayeb, Caroline
Pompei, Emanuela
Poulin-Girard, Anne-Sophie
Reshetov, Vladimir
Saint-Antoine, Jonathan
Sarajlic, Mirsad
Schnell, Robin
Segovia, Alex
Seidel, Julia
Silber, Armin
Sinclair, Peter
Sordet, Michael
Sosnowska, Danuta
Srivastava, Avidaan
Stefanov, Atanas K.
Teixeira, Márcio A.
Thibault, Simon
Vallée, Philippe
Vandal, Thomas
Vaulato, Valentina
Wehbe, Bachar
Weisserman, Drew
Wevers, Ivan
Wildi, François
Yariv, Vincent
Zins, Gérard
contents The intense stellar irradiation of ultra-hot Jupiters results in some of the most extreme atmospheric environments in the planetary regime. On their daysides, temperatures can be sufficiently high for key atmospheric constituents to thermally dissociate into simpler molecular species and atoms. This dissociation drastically changes the atmospheric opacities and, in turn, critically alters the temperature structure, atmospheric dynamics, and day-night heat transport. To this date, however, simultaneous detections of the dissociating species and their thermally dissociation products in exoplanet atmospheres have remained rare. Here we present the simultaneous detections of H$_2$O and its thermally dissociation product OH on the dayside of the ultra-hot Jupiter WASP-121 b based on high-resolution emission spectroscopy with the recently commissioned Near InfraRed Planet Searcher (NIRPS). We retrieve a photospheric abundance ratio of log$_{10}$(OH/H$_2$O) $= -0.15\pm{0.20}$ indicating that there is about as much OH as H$_2$O at photospheric pressures, which confirms predictions from chemical equilibrium models. We compare the dissociation on WASP-121 b with other ultra-hot Jupiters and show that a trend in agreement with equilibrium models arises. We also discuss an apparent velocity shift of $4.79^{+0.93}_{-0.97} $km s$^{-1}$ in the H$_2$O signal, which is not reproduced by current global circulation models. Finally, in addition to H$_2$O and OH, the NIRPS data reveal evidence of Fe and Mg, from which we infer a Fe/Mg ratio consistent with the solar and host star ratios. Our results demonstrate that NIRPS can be an excellent instrument to obtain simultaneous measurements of refractory and volatile molecular species, paving the way for many future studies on the atmospheric composition, chemistry, and the formation history of close-in exoplanets.
format Preprint
id arxiv_https___arxiv_org_abs_2508_06626
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Quantifying thermal water dissociation in the dayside photosphere of WASP-121 b using NIRPS
Bazinet, Luc
Allart, Romain
Benneke, Björn
Pelletier, Stefan
Wardenier, Joost P.
Cook, Neil J.
Forveille, Thierry
Nielsen, Louise D.
Moulla, Khaled Al
Artigau, Étienne
Baron, Frédérique
Barros, Susana C. C.
Bonfils, Xavier
Bouchy, François
Bryan, Marta
Martins, Bruno L. Canto
Cloutier, Ryan
Cowan, Nicolas B.
de Freitas, Daniel Brito
De Medeiros, Jose Renan
Delfosse, Xavier
Doyon, René
Dumusque, Xavier
Ehrenreich, David
Hernández, Jonay I. González
Lafrenière, David
Leão, Izan de Castro
Lovis, Christophe
Malo, Lison
Melo, Claudio
Mignon, Lucile
Mordasini, Christoph
Pepe, Francesco
Rebolo, Rafael
Rowe, Jason
Santos, Nuno C.
Ségransan, Damien
Mascareño, Alejandro Suárez
Udry, Stéphane
Valencia, Diana
Wade, Gregg
Abreu, Manuel
Aguiar, José L. A.
Allain, Guillaume
Arial, Tomy
Auger, Hugues
Blind, Nicolas
Bohlender, David
Boucher, Anne
Bourrier, Vincent
Bovay, Sébastien
Broeg, Christopher
Brousseau, Denis
Cabral, Alexandre
Cadieux, Charles
Carmona, Andres
Challita, Zalpha
Chazelas, Bruno
Coelho, João
Cointepas, Marion
Silva, Ana Rita Costa
Coulombe, Louis-Philippe
Cristo, Eduardo
Darveau-Bernier, Antoine
Dauplaise, Laurie
Gomes, Roseane de Lima
Fontinele, Dasaev O.
Frensch, Yolanda G. C.
Genest, Frédéric
Genolet, Ludovic
Témich, Félix Gracia
Hernandez, Olivier
Hoeijmakers, H. Jens
Hubin, Norbert
Jayawardhana, Ray
Käufl, Hans-Ulrich
Kerley, Dan
Kolb, Johann
Krishnamurthy, Vigneshwaran
Kung, Benjamin
Lamontagne, Pierrot
Lim, Olivia
Curto, Gaspare Lo
Rasilla, José Luis
Martins, Allan M.
Matthews, Jaymie
Mayer, Jean-Sébastien
Messias, Yuri S.
Metchev, Stan
Mounzer, Dany
Nari, Nicola
Osborn, Ares
Ouellet, Mathieu
Parc, Léna
Pasquini, Luca
Peroux, Céline
Piaulet-Ghorayeb, Caroline
Pompei, Emanuela
Poulin-Girard, Anne-Sophie
Reshetov, Vladimir
Saint-Antoine, Jonathan
Sarajlic, Mirsad
Schnell, Robin
Segovia, Alex
Seidel, Julia
Silber, Armin
Sinclair, Peter
Sordet, Michael
Sosnowska, Danuta
Srivastava, Avidaan
Stefanov, Atanas K.
Teixeira, Márcio A.
Thibault, Simon
Vallée, Philippe
Vandal, Thomas
Vaulato, Valentina
Wehbe, Bachar
Weisserman, Drew
Wevers, Ivan
Wildi, François
Yariv, Vincent
Zins, Gérard
Earth and Planetary Astrophysics
The intense stellar irradiation of ultra-hot Jupiters results in some of the most extreme atmospheric environments in the planetary regime. On their daysides, temperatures can be sufficiently high for key atmospheric constituents to thermally dissociate into simpler molecular species and atoms. This dissociation drastically changes the atmospheric opacities and, in turn, critically alters the temperature structure, atmospheric dynamics, and day-night heat transport. To this date, however, simultaneous detections of the dissociating species and their thermally dissociation products in exoplanet atmospheres have remained rare. Here we present the simultaneous detections of H$_2$O and its thermally dissociation product OH on the dayside of the ultra-hot Jupiter WASP-121 b based on high-resolution emission spectroscopy with the recently commissioned Near InfraRed Planet Searcher (NIRPS). We retrieve a photospheric abundance ratio of log$_{10}$(OH/H$_2$O) $= -0.15\pm{0.20}$ indicating that there is about as much OH as H$_2$O at photospheric pressures, which confirms predictions from chemical equilibrium models. We compare the dissociation on WASP-121 b with other ultra-hot Jupiters and show that a trend in agreement with equilibrium models arises. We also discuss an apparent velocity shift of $4.79^{+0.93}_{-0.97} $km s$^{-1}$ in the H$_2$O signal, which is not reproduced by current global circulation models. Finally, in addition to H$_2$O and OH, the NIRPS data reveal evidence of Fe and Mg, from which we infer a Fe/Mg ratio consistent with the solar and host star ratios. Our results demonstrate that NIRPS can be an excellent instrument to obtain simultaneous measurements of refractory and volatile molecular species, paving the way for many future studies on the atmospheric composition, chemistry, and the formation history of close-in exoplanets.
title Quantifying thermal water dissociation in the dayside photosphere of WASP-121 b using NIRPS
topic Earth and Planetary Astrophysics
url https://arxiv.org/abs/2508.06626