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Auteurs principaux: Redolat, Javier, Lozano, Miguel Sinusia, Pérez, María Camarena, González-Llácer, Ignacio, Zorina, Sofiya, Zafra, Eva, Chornet, Mar Alonso, Díaz-Escobar, Evelyn, Gómez, Víctor J., Martínez, Alejandro, Pinilla-Cienfuegos, Elena
Format: Preprint
Publié: 2025
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Accès en ligne:https://arxiv.org/abs/2508.11830
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author Redolat, Javier
Lozano, Miguel Sinusia
Pérez, María Camarena
González-Llácer, Ignacio
Zorina, Sofiya
Zafra, Eva
Chornet, Mar Alonso
Díaz-Escobar, Evelyn
Gómez, Víctor J.
Martínez, Alejandro
Pinilla-Cienfuegos, Elena
author_facet Redolat, Javier
Lozano, Miguel Sinusia
Pérez, María Camarena
González-Llácer, Ignacio
Zorina, Sofiya
Zafra, Eva
Chornet, Mar Alonso
Díaz-Escobar, Evelyn
Gómez, Víctor J.
Martínez, Alejandro
Pinilla-Cienfuegos, Elena
contents We present a hybrid surface-enhanced Raman spectroscopy (SERS) platform based on dielectric silicon metasurfaces integrated with functionalized graphene for the selective detection of biomolecules such as prolactin and SARS-CoV-2 antibodies. The metasurface comprises subwavelength silicon nanopillars that support Mie-type optical resonances, enabling strong electromagnetic field confinement with minimal heating and optical losses. Graphene monolayers are transferred onto the dielectric metasurface and functionalized using 1-pyrenebutanoic acid succinimidyl ester (PBASE), facilitating the selective immobilization of target antibodies via $π$-$π$ interactions and covalent bonding. Graphene transfer, functionalization, and analyte binding are confirmed by the SERS enhancement, which enables label-free detection at low laser power, avoiding photodamage and ensuring compatibility with sensitive biomolecules. Strain and doping analysis, performed through Raman vector decomposition, reveals distinct responses associated with each antibody, validating the sensor's capability for molecular discrimination.
format Preprint
id arxiv_https___arxiv_org_abs_2508_11830
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Hybrid Dielectric-Graphene SERS Metasurfaces for Antibody Sensing
Redolat, Javier
Lozano, Miguel Sinusia
Pérez, María Camarena
González-Llácer, Ignacio
Zorina, Sofiya
Zafra, Eva
Chornet, Mar Alonso
Díaz-Escobar, Evelyn
Gómez, Víctor J.
Martínez, Alejandro
Pinilla-Cienfuegos, Elena
Optics
We present a hybrid surface-enhanced Raman spectroscopy (SERS) platform based on dielectric silicon metasurfaces integrated with functionalized graphene for the selective detection of biomolecules such as prolactin and SARS-CoV-2 antibodies. The metasurface comprises subwavelength silicon nanopillars that support Mie-type optical resonances, enabling strong electromagnetic field confinement with minimal heating and optical losses. Graphene monolayers are transferred onto the dielectric metasurface and functionalized using 1-pyrenebutanoic acid succinimidyl ester (PBASE), facilitating the selective immobilization of target antibodies via $π$-$π$ interactions and covalent bonding. Graphene transfer, functionalization, and analyte binding are confirmed by the SERS enhancement, which enables label-free detection at low laser power, avoiding photodamage and ensuring compatibility with sensitive biomolecules. Strain and doping analysis, performed through Raman vector decomposition, reveals distinct responses associated with each antibody, validating the sensor's capability for molecular discrimination.
title Hybrid Dielectric-Graphene SERS Metasurfaces for Antibody Sensing
topic Optics
url https://arxiv.org/abs/2508.11830