The Missing Giant: Do FAST Spectroscopic Observations Reveal a Scarcity of Large Polycyclic Aromatic Hydrocarbons in Astronomical Environments?

Fuente: arXiv
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Main Authors: Shao, Yi, Zhang, Yong, Ouyang, Xu-Jia, Zhang, Chuan-Peng
Format: Preprint
Published: 2025
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author Shao, Yi
Zhang, Yong
Ouyang, Xu-Jia
Zhang, Chuan-Peng
author_facet Shao, Yi
Zhang, Yong
Ouyang, Xu-Jia
Zhang, Chuan-Peng
contents The search for large polycyclic aromatic hydrocarbons (PAHs) with over 100 carbon atoms is crucial to resolving the origin of unidentified infrared emission (UIE) bands. These bands are commonly observed in nebulae and the interstellar medium, yet their spectroscopic assignment has remained unknown for decades. Using the Five-hundred-meter Aperture Spherical Radio Telescope (FAST), the world's most sensitive instrument operating in the decimeter-wavelength range, we conducted a search for rotational transitions of large, quasi-symmetric PAHs. Our sample included two prototypical UIE sources, NGC 7027 and TMC-1, along with a non-UIE source, IRC+10216, for comparison. A matched filter technique was employed to isolate comb-like spectral features from quasi-symmetric PAHs containing 138 to 194 carbon atoms in the FAST spectra. This method significantly enhanced detection sensitivity to these astrophysically critical molecular signatures. Although no such features were detected, we derived upper limits on the abundance of large PAHs based on simplifying assumptions. These upper limits are lower than the values predicted by theoretical models, which might tentatively suggest that large PAHs may not be the primary carriers of UIE bands. However, this conclusion should be treated as tentative, given that it rests on simplistic assumptions which have not been empirically validated.
format Preprint
id arxiv_https___arxiv_org_abs_2508_15302
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle The Missing Giant: Do FAST Spectroscopic Observations Reveal a Scarcity of Large Polycyclic Aromatic Hydrocarbons in Astronomical Environments?
Shao, Yi
Zhang, Yong
Ouyang, Xu-Jia
Zhang, Chuan-Peng
Astrophysics of Galaxies
Solar and Stellar Astrophysics
The search for large polycyclic aromatic hydrocarbons (PAHs) with over 100 carbon atoms is crucial to resolving the origin of unidentified infrared emission (UIE) bands. These bands are commonly observed in nebulae and the interstellar medium, yet their spectroscopic assignment has remained unknown for decades. Using the Five-hundred-meter Aperture Spherical Radio Telescope (FAST), the world's most sensitive instrument operating in the decimeter-wavelength range, we conducted a search for rotational transitions of large, quasi-symmetric PAHs. Our sample included two prototypical UIE sources, NGC 7027 and TMC-1, along with a non-UIE source, IRC+10216, for comparison. A matched filter technique was employed to isolate comb-like spectral features from quasi-symmetric PAHs containing 138 to 194 carbon atoms in the FAST spectra. This method significantly enhanced detection sensitivity to these astrophysically critical molecular signatures. Although no such features were detected, we derived upper limits on the abundance of large PAHs based on simplifying assumptions. These upper limits are lower than the values predicted by theoretical models, which might tentatively suggest that large PAHs may not be the primary carriers of UIE bands. However, this conclusion should be treated as tentative, given that it rests on simplistic assumptions which have not been empirically validated.
title The Missing Giant: Do FAST Spectroscopic Observations Reveal a Scarcity of Large Polycyclic Aromatic Hydrocarbons in Astronomical Environments?
topic Astrophysics of Galaxies
Solar and Stellar Astrophysics
url https://arxiv.org/abs/2508.15302