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Main Authors: Vu, Dung, Lee, Hangoo, Nicoletti, Daniele, Wei, Wenzheng, Jin, Zheting, Chichinadze, Dmitry V., Buzzi, Michele, Li, Wenxin, Yang, Xinhao, Wu, Rongting, Mizzi, Christopher A., Qian, Tiema, Maiorov, Boris, Suslov, Alexey, He, Yu, Lewandowski, Cyprian, Ismail-Beigi, Sohrab, Walker, Frederick, Cavalleri, Andrea, Ahn, Charles
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2508.15968
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author Vu, Dung
Lee, Hangoo
Nicoletti, Daniele
Wei, Wenzheng
Jin, Zheting
Chichinadze, Dmitry V.
Buzzi, Michele
Li, Wenxin
Yang, Xinhao
Wu, Rongting
Mizzi, Christopher A.
Qian, Tiema
Maiorov, Boris
Suslov, Alexey
He, Yu
Lewandowski, Cyprian
Ismail-Beigi, Sohrab
Walker, Frederick
Cavalleri, Andrea
Ahn, Charles
author_facet Vu, Dung
Lee, Hangoo
Nicoletti, Daniele
Wei, Wenzheng
Jin, Zheting
Chichinadze, Dmitry V.
Buzzi, Michele
Li, Wenxin
Yang, Xinhao
Wu, Rongting
Mizzi, Christopher A.
Qian, Tiema
Maiorov, Boris
Suslov, Alexey
He, Yu
Lewandowski, Cyprian
Ismail-Beigi, Sohrab
Walker, Frederick
Cavalleri, Andrea
Ahn, Charles
contents High temperature superconductivity is typically associated with strong coupling and a large superconducting gap, yet these characteristics have not been demonstrated in the nickelates. Here, we provide experimental evidence that Eu substitution in the spacer layer of Nd1-xEuxNiO2 (NENO) thin films enhances the superconducting gap, driving the system toward a strong-coupling regime. This is accompanied by a magnetic-exchange-driven magnetic-field-enhanced superconductivity. We investigate the upper critical magnetic field, Hc2, and superconducting gap of superconducting NENO thin films with x=0.2 to 0.35. Magnetoresistance measurements reveal magnetic-field-enhanced superconductivity in NENO films. We interpret this phenomenon as a result of interaction between magnetic Eu ions and superconducting states in the Ni dx2-y2 orbital. The upper critical magnetic field strongly violates the weak-coupling Pauli limit. Infrared spectroscopy confirms a large gap-to-Tc ratio $2 Δk_B T_c \approx 5 - 6$, indicating a stronger coupling pairing mechanism in NENO relative to the Sr-doped NdNiO2. The substitution of Eu in the rare-earth layer provides a method to modify the superconducting gap in Nd-based nickelates, an essential factor in engineering high-Tc superconductivity in infinite-layer nickelates.
format Preprint
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institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Re-entrant unconventional superconductivity induced by rare-earth substitution in Nd1-xEuxNiO2 thin films
Vu, Dung
Lee, Hangoo
Nicoletti, Daniele
Wei, Wenzheng
Jin, Zheting
Chichinadze, Dmitry V.
Buzzi, Michele
Li, Wenxin
Yang, Xinhao
Wu, Rongting
Mizzi, Christopher A.
Qian, Tiema
Maiorov, Boris
Suslov, Alexey
He, Yu
Lewandowski, Cyprian
Ismail-Beigi, Sohrab
Walker, Frederick
Cavalleri, Andrea
Ahn, Charles
Superconductivity
High temperature superconductivity is typically associated with strong coupling and a large superconducting gap, yet these characteristics have not been demonstrated in the nickelates. Here, we provide experimental evidence that Eu substitution in the spacer layer of Nd1-xEuxNiO2 (NENO) thin films enhances the superconducting gap, driving the system toward a strong-coupling regime. This is accompanied by a magnetic-exchange-driven magnetic-field-enhanced superconductivity. We investigate the upper critical magnetic field, Hc2, and superconducting gap of superconducting NENO thin films with x=0.2 to 0.35. Magnetoresistance measurements reveal magnetic-field-enhanced superconductivity in NENO films. We interpret this phenomenon as a result of interaction between magnetic Eu ions and superconducting states in the Ni dx2-y2 orbital. The upper critical magnetic field strongly violates the weak-coupling Pauli limit. Infrared spectroscopy confirms a large gap-to-Tc ratio $2 Δk_B T_c \approx 5 - 6$, indicating a stronger coupling pairing mechanism in NENO relative to the Sr-doped NdNiO2. The substitution of Eu in the rare-earth layer provides a method to modify the superconducting gap in Nd-based nickelates, an essential factor in engineering high-Tc superconductivity in infinite-layer nickelates.
title Re-entrant unconventional superconductivity induced by rare-earth substitution in Nd1-xEuxNiO2 thin films
topic Superconductivity
url https://arxiv.org/abs/2508.15968