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Main Authors: Irfan, Shaheen, Ahmad, Zaki, Akbar, Nosheen, Mansoor, Minal, Sumbul, Hussnain
Format: Preprint
Published: 2025
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Online Access:https://arxiv.org/abs/2508.17133
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author Irfan, Shaheen
Ahmad, Zaki
Akbar, Nosheen
Mansoor, Minal
Sumbul, Hussnain
author_facet Irfan, Shaheen
Ahmad, Zaki
Akbar, Nosheen
Mansoor, Minal
Sumbul, Hussnain
contents In this work, the energy eigenvalues are calculated for the quadratic ($\frac{g^2 x^2}{2}$), pure quartic ($λx^4 $), and quartic anharmonic oscillators ($\frac{g^2 x^2}{2} + λx^4 $) by applying variational method. For this, simple harmonic oscillator wave functions are considered as trial wave functions to calculate the energies for the ground state and first ten excited states with $g = 1$ and $λ=1/4$. For quartic anharmonic oscillators, energy values are calculated at different values of $λ$ with $g=1$. These energies for the ground state are compared with available numerically calculated data. Maximum value of $\%$error is found to be 1.9977. To get more accurate results, a new set of trial wave functions is suggested. With the newly proposed wave functions, maximum value of $\%$ error for the energy values reduces to 0.561. In this work, energies for the ground and first five excited states of quartic anharmonic oscillators are reported at different values of $λ$. Dependence of $λ$ on the wave functions is observed and concluded that wave functions are converging (shrinking) by increasing the $λ$.
format Preprint
id arxiv_https___arxiv_org_abs_2508_17133
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Energy eigenvalues of quadratic, pure quartic and quartic anharmonic oscillators with variational method
Irfan, Shaheen
Ahmad, Zaki
Akbar, Nosheen
Mansoor, Minal
Sumbul, Hussnain
Quantum Physics
In this work, the energy eigenvalues are calculated for the quadratic ($\frac{g^2 x^2}{2}$), pure quartic ($λx^4 $), and quartic anharmonic oscillators ($\frac{g^2 x^2}{2} + λx^4 $) by applying variational method. For this, simple harmonic oscillator wave functions are considered as trial wave functions to calculate the energies for the ground state and first ten excited states with $g = 1$ and $λ=1/4$. For quartic anharmonic oscillators, energy values are calculated at different values of $λ$ with $g=1$. These energies for the ground state are compared with available numerically calculated data. Maximum value of $\%$error is found to be 1.9977. To get more accurate results, a new set of trial wave functions is suggested. With the newly proposed wave functions, maximum value of $\%$ error for the energy values reduces to 0.561. In this work, energies for the ground and first five excited states of quartic anharmonic oscillators are reported at different values of $λ$. Dependence of $λ$ on the wave functions is observed and concluded that wave functions are converging (shrinking) by increasing the $λ$.
title Energy eigenvalues of quadratic, pure quartic and quartic anharmonic oscillators with variational method
topic Quantum Physics
url https://arxiv.org/abs/2508.17133