Amorphous $CaSO_{4}$ nanocrystal deposits for friction and wear reduction at silicon interfaces

Fuente: arXiv
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Autori principali: Vernooij, Tijn, Çiftçi, Tunç, Shahidzadeh, Noushine, Weber, Bart
Natura: Preprint
Pubblicazione: 2025
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author Vernooij, Tijn
Çiftçi, Tunç
Shahidzadeh, Noushine
Weber, Bart
author_facet Vernooij, Tijn
Çiftçi, Tunç
Shahidzadeh, Noushine
Weber, Bart
contents When an object is placed on a surface, friction and wear cause uncertainty in its exact position, and thus challenge precision manufacturing. Here, we explore the development of a sacrificial nanocrystal deposit that can suppress friction and wear. Amorphous \ce{CaSO4} nancrystals are deposited through salt solution droplet deposition followed by evaporation. During droplet drying, a precursor film of the aqueous \ce{CaSO4} solution spreads onto a hydrophilic silicon wafer, thus nucleating evenly spread unfaceted amorphous nanocrystals of \ce{CaSO4} on the wafer surface. We used atomic force microscopy to study the extent, topography, and friction and wear behavior of the deposited nanocrystals. We find that the sacrificial layer of nanocrystals is easy to apply and remove, spreads over large (few cm) areas with a constant thickness of about 8 nm, and has favorable friction and wear behavior.
format Preprint
id arxiv_https___arxiv_org_abs_2508_17869
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Amorphous $CaSO_{4}$ nanocrystal deposits for friction and wear reduction at silicon interfaces
Vernooij, Tijn
Çiftçi, Tunç
Shahidzadeh, Noushine
Weber, Bart
Soft Condensed Matter
When an object is placed on a surface, friction and wear cause uncertainty in its exact position, and thus challenge precision manufacturing. Here, we explore the development of a sacrificial nanocrystal deposit that can suppress friction and wear. Amorphous \ce{CaSO4} nancrystals are deposited through salt solution droplet deposition followed by evaporation. During droplet drying, a precursor film of the aqueous \ce{CaSO4} solution spreads onto a hydrophilic silicon wafer, thus nucleating evenly spread unfaceted amorphous nanocrystals of \ce{CaSO4} on the wafer surface. We used atomic force microscopy to study the extent, topography, and friction and wear behavior of the deposited nanocrystals. We find that the sacrificial layer of nanocrystals is easy to apply and remove, spreads over large (few cm) areas with a constant thickness of about 8 nm, and has favorable friction and wear behavior.
title Amorphous $CaSO_{4}$ nanocrystal deposits for friction and wear reduction at silicon interfaces
topic Soft Condensed Matter
url https://arxiv.org/abs/2508.17869