Quantum Process Tomography of a Thermal Alkali-Metal Vapor

Fuente: arXiv
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Main Authors: Sun, Yujie, Kopciuch, Marek, Fard, Arash Dezhang, Pustelny, Szymon
Format: Preprint
Published: 2025
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author Sun, Yujie
Kopciuch, Marek
Fard, Arash Dezhang
Pustelny, Szymon
author_facet Sun, Yujie
Kopciuch, Marek
Fard, Arash Dezhang
Pustelny, Szymon
contents Characterizing the open-system dynamics of multilevel quantum systems (qudits) remains a fundamental challenge due to ensemble inhomogeneities and complex environmental interactions. Here, we introduce a computationally efficient quantum process tomography framework that reconstructs the Liouvillian dynamics of a thermal $^{87}$Rb qutrit ensemble directly in the Bloch-Fano representation. By combining maximum likelihood estimation with post-hoc spectral regularization, our protocol extracts physically admissible, completely positive and trace-preserving maps without repeated numerical integration of the master equation. We rigorously justify selecting the principal branch for the matrix logarithm by demonstrating that experimental eigenvalue phases remain strictly bounded within $[-0.35,0.35]$ radians, avoiding branch-cut ambiguities. The method is validated across relaxation-driven, static-field, and time-dependent regimes, resolving overlapping control signals and subtle dissipative mechanisms such as AC Stark shifts. Our approach establishes a scalable route for generator-level characterization of ambient qudit systems, enabling noise-aware control and precise benchmarking for atomic sensors and simulators.
format Preprint
id arxiv_https___arxiv_org_abs_2508_19634
institution arXiv
publishDate 2025
record_format arxiv
spellingShingle Quantum Process Tomography of a Thermal Alkali-Metal Vapor
Sun, Yujie
Kopciuch, Marek
Fard, Arash Dezhang
Pustelny, Szymon
Quantum Physics
Applied Physics
Atomic Physics
Optics
Characterizing the open-system dynamics of multilevel quantum systems (qudits) remains a fundamental challenge due to ensemble inhomogeneities and complex environmental interactions. Here, we introduce a computationally efficient quantum process tomography framework that reconstructs the Liouvillian dynamics of a thermal $^{87}$Rb qutrit ensemble directly in the Bloch-Fano representation. By combining maximum likelihood estimation with post-hoc spectral regularization, our protocol extracts physically admissible, completely positive and trace-preserving maps without repeated numerical integration of the master equation. We rigorously justify selecting the principal branch for the matrix logarithm by demonstrating that experimental eigenvalue phases remain strictly bounded within $[-0.35,0.35]$ radians, avoiding branch-cut ambiguities. The method is validated across relaxation-driven, static-field, and time-dependent regimes, resolving overlapping control signals and subtle dissipative mechanisms such as AC Stark shifts. Our approach establishes a scalable route for generator-level characterization of ambient qudit systems, enabling noise-aware control and precise benchmarking for atomic sensors and simulators.
title Quantum Process Tomography of a Thermal Alkali-Metal Vapor
topic Quantum Physics
Applied Physics
Atomic Physics
Optics
url https://arxiv.org/abs/2508.19634