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| Format: | Preprint |
| Published: |
2025
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| Online Access: | https://arxiv.org/abs/2508.21607 |
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| _version_ | 1866915474387763200 |
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| author | Lutsko, James F. |
| author_facet | Lutsko, James F. |
| contents | The general, multidimensional barrier crossing problem for diffusive processes under the action of conservative forces is studied with the goal of developing tractable approximations. Particular attention is given to the effect of different statistical interpretations of the stochastic differential equation and to the relation between the approximations and the known, exact solutions to the one-dimensional problem. Beginning with a reasonable, but heuristic, simplifying assumption, a one-dimensional solution to the problem is developed. This is then simplified by introducing further approximations resulting in a sequence of increasingly simple expressions culminating in the classic result of Langer(Ann. Phys. 54, 258 (1969)) and others. The various approximations are tested on two dimensional problems by comparison to simulation results and it is found that the one-dimensional approximations capture most of the non-Arrhenius dependence on the energy barrier which is lost in the Langer approximation while still converging to the latter in the large-barrier limit. |
| format | Preprint |
| id |
arxiv_https___arxiv_org_abs_2508_21607 |
| institution | arXiv |
| publishDate | 2025 |
| record_format | arxiv |
| spellingShingle | Approximate calculation of multidimensional first passage times Lutsko, James F. Statistical Mechanics Chemical Physics The general, multidimensional barrier crossing problem for diffusive processes under the action of conservative forces is studied with the goal of developing tractable approximations. Particular attention is given to the effect of different statistical interpretations of the stochastic differential equation and to the relation between the approximations and the known, exact solutions to the one-dimensional problem. Beginning with a reasonable, but heuristic, simplifying assumption, a one-dimensional solution to the problem is developed. This is then simplified by introducing further approximations resulting in a sequence of increasingly simple expressions culminating in the classic result of Langer(Ann. Phys. 54, 258 (1969)) and others. The various approximations are tested on two dimensional problems by comparison to simulation results and it is found that the one-dimensional approximations capture most of the non-Arrhenius dependence on the energy barrier which is lost in the Langer approximation while still converging to the latter in the large-barrier limit. |
| title | Approximate calculation of multidimensional first passage times |
| topic | Statistical Mechanics Chemical Physics |
| url | https://arxiv.org/abs/2508.21607 |